Systems of first-order chemical reactions (Q1116923)
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English | Systems of first-order chemical reactions |
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Systems of first-order chemical reactions (English)
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1988
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A reaction system where every species of a finite number of species reacts by first order to every other species is investigated. The convergence behaviour of the solution of the corresponding initial value problem \(dx/dt=Kx\), where x stands for the vector of concentrations and K is the matrix that results from the rate constants, is studied in respect to properties of K that reflect special forms of reaction schemes. In particular, the significance of the principle of microscopic reversibility for the non-existence of oscillatory solutions is pointed out.
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linear chemical system
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first-order kinetics
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reaction system
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finite number of species
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reaction schemes
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principle of microscopic reversibility
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non-existence of oscillatory solutions
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