On the Born-Oppenheimer approximation for excited states of polyatomic Schrödinger operators (Q1196103)

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On the Born-Oppenheimer approximation for excited states of polyatomic Schrödinger operators
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    On the Born-Oppenheimer approximation for excited states of polyatomic Schrödinger operators (English)
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    10 November 1992
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    Let \(h^ 2\) denote the ratio of electronic and nuclear masses, in a polyatomic molecule, then it is shown that under some assumptions of non- degeneracy, certain low-lying energy levels of the system admit asymptotic expansions in powers of \(h\). The author uses the techniques introduced by Klein-Martinez-Seiler-Wang, and generalizes a result of Helffer-Sjöstrand on semiclassical manifold-wells.
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    Born-Oppenheimer approximation
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    polyatomic molecule
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    low-lying energy levels
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    asymptotic expansions
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