Rotation-vibration-dissociation interaction in a multicomponent nonequilibrium viscous shock layer (Q1815188)

A new, simple and physically adequate method of calculating vibrationally nonequilibrium dissociation constants is proposed on the basis of a dissociation model which takes into account the equilibrium excitation of the rotational degrees of freedom of the molecules and the nonequilibrium excitation of vibrational quantum states. This rotation-vibration-dissociation interaction model contains only the indeterminacy associated with the indeterminacy of the experimental data on the interaction potential and the collision cross-sections of the components. In the case of thermodynamic equilibrium the model gives values of the dissociation constants close to those generally accepted. The use of this model in multicomponent nonequilibrium total viscous shock layer calculations gives values for the shock detachment distance within \(5\%\) of the experimental values.