The Fermi-Dirac distribution as a model of a thermodynamically ideal liquid. Phase transition of the first kind for neutral gases (corresponding to nonpolar molecules) (Q2396395)

Using the notion of entropy in enlarged number theory, this paper calculates the temperature below which thermodynamically ideal liquid appears. This model is convenient as in the region of positive pressures and in the particular case \(Z_c=3/8\), it provides a good agreement with the van der Waals model and can be extended to a gas model with nonpolar molecules. By running the MATLAB program using Bose statistics, the temperature is found to be \(T=0.84T_c\), where \(T_c\) is the critical temperature of a gas whose molecules are nonpolar. Parastatistics are then used to obtain an agreement between the theoretical isotherms and the isotherms of a van der Waals gas at higher temperatures. A new phase transition of the second kind at the point of zero activity is described using tropical analysis.