vibrational frequency shift (1st order) (Q6674548)
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frequency shift of molecular vibrations caused by interaction with surrounding particles from 1st order non-degenerate perturbation theory
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| default for all languages | No label defined |
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| English | vibrational frequency shift (1st order) |
frequency shift of molecular vibrations caused by interaction with surrounding particles from 1st order non-degenerate perturbation theory |
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The interpretation is quite straight-forward: Effectively, the intermolecular potential changes the effective force constant of a vibrational normal mode.
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