quantum Hamiltonian (symmetric top) (Q6674552)

From MaRDI portal
!
WARNING

This is the item page for this Wikibase entity, intended for internal use and editing purposes.

quantum-mechanical represention of a molecule as a symmetric top
Language Label Description Also known as
default for all languages
No label defined
    English
    quantum Hamiltonian (symmetric top)
    quantum-mechanical represention of a molecule as a symmetric top

      Statements

      Ĥ=AJÂ2+BJB̂2+CJĈ2
      0 references
      0 references
      A symmetric top is a molecule in which two moments of inertia are the same. By definition a symmetric top must have a 3-fold or higher order rotation axis. In practice, spectroscopists divide molecules into two classes of symmetric tops: Oblate symmetric tops (saucer or disc shaped), e.g., C6H6, and Prolate symmetric tops (rugby football, or cigar shaped), e.g. CH3Cl.
      0 references
      0 references