light particle nonadiabatic coupling (first order) (Q6775400)

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first order nonadiabatic coupling of the light particle(s) quantum states induced by heavy particle(s) dynamics in quantum-classical models
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    light particle nonadiabatic coupling (first order)
    first order nonadiabatic coupling of the light particle(s) quantum states induced by heavy particle(s) dynamics in quantum-classical models

      Statements

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      dnmk≡⟨ϕn(R)|∇Rk|ϕm(R)⟩rdnnk=0dnmk=−(dmnk)∗
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      Note that the first-order coupling tensor is anti-Hermitian with respect to interchange of the adiabatic state indices
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