Cluster and virial expansions for the multi-species Tonks gas (Q906938)
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English | Cluster and virial expansions for the multi-species Tonks gas |
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Cluster and virial expansions for the multi-species Tonks gas (English)
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1 February 2016
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The author deals with one-dimensional systems of non-overlapping rods on a continuous segment \([0,L]\) or a discrete interval \(\{0,1,\dots,L-1\}\). There are countably many types \(k\) of rods, coming each with a length \(l_k \geq 0\) and an activity \(z_k\). The main results of this paper are necessary and sufficient convergence criteria for the expansion of the pressure in terms of the activities \(z_k\) and the densities \(\rho_k\). The author provides explicit formulas for the pressure-activity expansion that are interesting from a combinatoric point of view. In the continuous case, the author finds that the activity expansion is (up to signs) the multivariate exponential generating function for labeled rooted colored trees. This generalizes the well-known relation between non-overlapping rods and labeled rooted trees. Noting that the key tool is the fixed point equation for the pressure, the author provides a physical explanation in terms of van der Waals mixtures and a probabilistic explanation in terms of renewal processes.
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cluster and virial expansions
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non-overlapping rods
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combinatorics of labelled colored trees
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close-packing transition
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fixed point equation for the pressure
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