Kiselev isotherm model

adsorption model for localized monolayer with complex formation

deterministic model, dimensional model, mathematical model, nonlinear model, static model

MaRDI QIDQ6820970FDOCommunityMathModDB

Named after

Description

The Kiselev isotherm model describes adsorption occurring in a localized monomolecular layer, where adsorbate molecules may form surface complexes with one another. Unlike the Langmuir model, Kiselev explicitly includes a complex-formation parameter that accounts for associations between adsorbed molecules at neighboring sites. This allows the model to represent cooperative or associative adsorption behavior on heterogeneous or interacting surfaces. It is used primarily to interpret adsorption on solids where pairwise interactions or dimer formation occurs. Applications include surface chemistry, catalysis, and environmental adsorption processes such as chemical wastewater treatment.

Contained entities

Kiselev equation	$k_{1} C_{e} = \frac{θ}{(1 - θ) (1 + k_{n} θ)}$
	$C_{e}$ represents solute concentration (equilibrium)
	$θ$ represents fractional surface coverage
	$k_{1}$ represents Kiselev equilibrium constant
	$k$ represents complex formation constant

Computational tasks

nonlinear parameter estimation (Kiselev model), linear parameter estimation (Kiselev model)

References

Monolayer and multilayer adsorption isotherm models for sorption from aqueous media	(review)

Further links

Item	Property
chemical wastewater treatment	modelled by

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