Linear parameter estimation (Kiselev model)

nonlinear estimation of Kiselev model parameters

MaRDI QIDQ6820972FDOCommunityMathModDB

Named after

Description

This task estimates the Kiselev equilibrium constant and the complex formation constant using the linearized form of the Kiselev isotherm. Experimental equilibrium coverage and concentration data are transformed and analyzed using linear regression. Although computationally simple, the approach may introduce bias due to data transformation. The estimated parameters describe adsorption affinity and the extent of complex formation among adsorbed species.

Contained entities

complex formation constant		output
solute concentration (equilibrium)		input
fractional surface coverage	$θ \equiv \frac{q_{e}}{q_{m}}$	input
	$θ \equiv \frac{V}{V_{m}}$
	$θ$ represents fractional surface coverage
	$q_{e}$ represents adsorbed solute (equilibrium)
	$q_{m}$ represents maximum monolayer adsorption capacity
	$V$ represents adsorbed gas volume (equlibrium)
	$V_{m}$ represents maximum monolayer adsorption volume

Kiselev equilibrium constant		output
linear Kiselev equation	$\frac{1}{C_{e} (1 - θ)} = \frac{k_{1}}{t h e t a} + k_{1} k_{n}$
	$C_{e}$ represents solute concentration (equilibrium)
	$θ$ represents fractional surface coverage
	$k_{1}$ represents Kiselev equilibrium constant
	$k_{n}$ represents complex formation constant

Further links

Item	Property
Kiselev isotherm model	used by
nonlinear parameter estimation (Kiselev model)	linearized by

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