linear rotor (non-rigid)

Community: MathModDB

mathematical model

Available identifiers

MaRDI QIDQ6675421

modeling a linear molecule as a non-rigid rotor, i.e., the bond between the atoms stretches out as the molecule rotates faster

List of contained entities

quantum Hamiltonian (non-rigid rotor)	$\hat{H}=B{\hat{J}}^2+D{\hat{J}}^4$
	$B$ represents rotational constant
	$D$ represents centrifugal distortion constant
	$H$ represents Hamiltonian operator
	$J$ represents angular momentum operator
quantum eigen energy (linear non-rigid rotor)	$E_j=Bj(j+1)-D{j}^2(j+1{)}^2$
	$B$ represents rotational constant
	$D$ represents centrifugal distortion constant
	$E_j$ represents quantum eigen energy
	$j$ represents quantum number

List of approximations

linear rotor

List of computational tasks

quantum stationary states

quantum time evolution

Further items linking to linear rotor (non-rigid)

Item	Property
molecular rotation	modelled by

This page was built for model: linear rotor (non-rigid)