Nonlinear parameter estimation (Koble-Corrigan model)

nonlinear estimation of hybrid isotherm parameters

Description

This task involves nonlinear regression of equilibrium adsorption data to estimate the parameters of the Koble-Corrigan isotherm model. Experimental measurements of equilibrium adsorbed amount and solute concentration are fitted to the model equation. The fitting procedure determines the constants, which control adsorption capacity and saturation behavior, as well as the heterogeneity exponent. The task is commonly used when adsorption occurs on heterogeneous surfaces and cannot be adequately described by simpler Langmuir or Freundlich models alone.

Contained entities

Koble-Corrigan constant A		output
solute concentration (equilibrium)		input
Koble-Corrigan heterogeneity exponent constraint	$n_{K} > 0$	constraint
	$n_{K}$ represents Koble-Corrigan heterogeneity exponent

adsorbed solute (equilibrium)		input
Koble-Corrigan constant B		output
Koble-Corrigan heterogeneity exponent		output
Koble-Corrigan isotherm equation	$q_{e} = \frac{A C_{e}^{n_{K}}}{B + C_{e}^{n_{K}}}$
	$C_{e}$ represents solute concentration (equilibrium)
	$q_{e}$ represents adsorbed solute (equilibrium)
	$A$ represents Koble-Corrigan constant A
	$B$ represents Koble-Corrigan constant B
	$n_{K}$ represents Koble-Corrigan heterogeneity exponent

Specializations

nonlinear parameter estimation (Langmuir adsorption model), linear parameter estimation (Freundlich isotherm), linear parameter estimation (Henry's isotherm)

Further links

Item	Property
Koble-Corrigan isotherm model	used by

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