nonlinear parameter estimation (Koble-Corrigan model)

Community: MathModDB

computational task

nonlinear task

Available identifiers

MaRDI QIDQ6821222 FDOQ6821222

nonlinear estimation of hybrid isotherm parameters

Description

This task involves nonlinear regression of equilibrium adsorption data to estimate the parameters of the Koble-Corrigan isotherm model. Experimental measurements of equilibrium adsorbed amount and solute concentration are fitted to the model equation. The fitting procedure determines the constants, which control adsorption capacity and saturation behavior, as well as the heterogeneity exponent. The task is commonly used when adsorption occurs on heterogeneous surfaces and cannot be adequately described by simpler Langmuir or Freundlich models alone.

List of contained entities

Koble-Corrigan constant A
Koble-Corrigan constant B
Koble-Corrigan heterogeneity exponent
Koble-Corrigan heterogeneity exponent constraint	$n_K>0$	constraint
	$n_K$ represents Koble-Corrigan heterogeneity exponent
Koble-Corrigan isotherm equation	$q_e=\frac{A{C}_e^{n_K}}{B+C_e^{n_K}}$
	$C_e$ represents solute concentration (equilibrium)
	$q_e$ represents adsorbed solute (equilibrium)
	$A$ represents Koble-Corrigan constant A
	$B$ represents Koble-Corrigan constant B
	$n_K$ represents Koble-Corrigan heterogeneity exponent
adsorbed solute (equilibrium)
solute concentration (equilibrium)

Computational tasks specializing nonlinear parameter estimation (Koble-Corrigan model)

linear parameter estimation (Freundlich isotherm)

linear parameter estimation (Henry's isotherm)

nonlinear parameter estimation (Langmuir adsorption model)

Further items linking to nonlinear parameter estimation (Koble-Corrigan model)

Item	Property
Koble-Corrigan isotherm model	used by

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