Nonlinear parameter estimation (Langmuir adsorption model)

Langmuir adsorption model

Named after

Description

This task performs nonlinear parameter estimation using experimental adsorption equilibrium data. The objective is to determine the Langmuir adsorption constant and maximum monolayer adsorption capacity by fitting the nonlinear Langmuir equation directly to measured solute concentration and adsorbed amount data. The results quantify the adsorption affinity and monolayer capacity of the adsorbent without bias from linearization.

Contained entities

adsorbed solute (equilibrium)		input
maximum monolayer adsorption capacity		output
Langmuir adsorption constant	$K_{L} \equiv \frac{k_{a}}{k_{d}}$	output
	$K_{L}$ represents Langmuir adsorption constant
	$k_{a}$ represents adsorption rate constant
	$k_{d}$ represents desorption rate constant

solute concentration (equilibrium)		input
Langmuir equation	$q_{e} = \frac{q_{m} K_{L} C_{e}}{1 + K_{L} C_{e}}$
	$θ = \frac{K_{L} C_{e}}{1 + K_{L} C_{e}}$
	$q_{e} = \frac{q_{m} K_{L} p_{e}}{1 + K_{L} p_{e}}$
	$θ = \frac{K_{L} p_{e}}{1 + K_{L} p_{e}}$
	$q_{e}$ represents adsorbed solute (equilibrium)
	$C_{e}$ represents solute concentration (equilibrium)
	$K_{L}$ represents Langmuir adsorption constant
	$q_{m}$ represents maximum monolayer adsorption capacity
	$θ$ represents fractional surface coverage
	$p_{e}$ represents adsorbate partial pressure (equilibrium)

Further links

Item	Property
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nonlinear parameter estimation (Sips model)	specialized by
nonlinear parameter estimation (Toth model)	specialized by
nonlinear parameter estimation (UNILAN model)	specialized by

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