Nonlinear parameter estimation (Langmuir adsorption model)

Community: MathModDB

computational task	nonlinear task

Available identifiers

MaRDI QIDQ6775767 FDOQ6775767

named after Irving Langmuir

Description

This task performs nonlinear parameter estimation using experimental adsorption equilibrium data. The objective is to determine the Langmuir adsorption constant and maximum monolayer adsorption capacity by fitting the nonlinear Langmuir equation directly to measured solute concentration and adsorbed amount data. The results quantify the adsorption affinity and monolayer capacity of the adsorbent without bias from linearization.

Contained entities

Further linked items

Item	Property
Langmuir adsorption model	used by
nonlinear parameter estimation (Fritz-Schlunder 4-parameter model)	specialized by
nonlinear parameter estimation (Frumkin model)	specialized by
nonlinear parameter estimation (Khan model)	specialized by
nonlinear parameter estimation (Koble-Corrigan model)	specialized by
nonlinear parameter estimation (Radke-Prausnitz model)	specialized by
nonlinear parameter estimation (Redlich-Peterson model)	specialized by
nonlinear parameter estimation (Sips model)	specialized by
nonlinear parameter estimation (Toth model)	specialized by
nonlinear parameter estimation (UNILAN model)	specialized by

Edit nonlinear parameter estimation (Langmuir adsorption model) item

This page was built for task: nonlinear parameter estimation (Langmuir adsorption model)

solute concentration (equilibrium)
adsorbed solute (equilibrium)
maximum monolayer adsorption capacity
Langmuir adsorption constant	$K_{L} \equiv \frac{k_{a}}{k_{d}}$	output
	$K_{L}$ represents Langmuir adsorption constant
	$k_{a}$ represents adsorption rate constant
	$k_{d}$ represents desorption rate constant

Langmuir equation	$q_{e} = \frac{q_{m} K_{L} C_{e}}{1 + K_{L} C_{e}}$
	$θ = \frac{K_{L} C_{e}}{1 + K_{L} C_{e}}$
	$q_{e} = \frac{q_{m} K_{L} p_{e}}{1 + K_{L} p_{e}}$
	$θ = \frac{K_{L} p_{e}}{1 + K_{L} p_{e}}$
	$q_{e}$ represents adsorbed solute (equilibrium)
	$C_{e}$ represents solute concentration (equilibrium)
	$K_{L}$ represents Langmuir adsorption constant
	$q_{m}$ represents maximum monolayer adsorption capacity
	$θ$ represents fractional surface coverage
	$p_{e}$ represents adsorbate partial pressure (equilibrium)