nonlinear parameter estimation (UNILAN model)

Community: MathModDB

computational task	nonlinear task

Available identifiers

MaRDI QIDQ6821263 FDOQ6821263

nonlinear estimation of UNILAN adsorption parameters

Description

This task consists of estimating the UNILAN isotherm parameters by fitting the nonlinear UNILAN equation to experimental equilibrium adsorption data. The fitted parameters typically include the maximum adsorption capacity, the adsorption affinity constant, and the heterogeneity parameter. Nonlinear regression methods are required due to the logarithmic and exponential structure of the model. The task is commonly used to characterize surface heterogeneity and adsorption energetics in heterogeneous adsorbent systems.

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Computational tasks specializing nonlinear parameter estimation (UNILAN model)

nonlinear parameter estimation (Langmuir adsorption model)

Further items linking to nonlinear parameter estimation (UNILAN model)

Item	Property
UNILAN isotherm model	used by

This page was built for task: nonlinear parameter estimation (UNILAN model)

UNILAN adsorption affinity constant
UNILAN equation	$q_{e} = \frac{q_{m}}{2 s} \ln (\frac{1 + b e^{s} C_{e}}{1 + b e^{- s} C_{e}})$
	$q_{e}$ represents adsorbed solute (equilibrium)
	$C_{e}$ represents solute concentration (equilibrium)
	$q_{m}$ represents maximum monolayer adsorption capacity
	$b$ represents UNILAN adsorption affinity constant
	$s$ represents UNILAN heterogeneity parameter

UNILAN heterogeneity parameter
UNILAN heterogeneity parameter constraint	$s > 0$	constraint
	$s$ represents UNILAN heterogeneity parameter

adsorbed solute (equilibrium)
maximum monolayer adsorption capacity
solute concentration (equilibrium)