nonlinear parameter estimation (Sips model)

Community: MathModDB

computational task	nonlinear task

Available identifiers

MaRDI QIDQ6821136 FDOQ6821136

nonlinear estimation of Sips isotherm parameters

Description

This task performs nonlinear parameter estimation using adsorption equilibrium data. The objective is to determine the Sips maximum adsorption capacity, the Sips equilibrium constant, and the Sips heterogeneity exponent by fitting the nonlinear Sips equation directly to measured solute concentrations and adsorbed amounts. The nonlinear approach preserves the combined Langmuir-Freundlich behavior of the model and avoids distortions introduced by linearization. The results characterize both the adsorption affinity and the degree of surface heterogeneity governing the adsorption process.

List of contained entities

Sips equation	$q_{e} = q_{m} \frac{K_{S} C_{e}^{m}}{1 + K_{S} C_{e}^{m}}$
	$q_{e}$ represents adsorbed solute (equilibrium)
	$q_{m}$ represents maximum monolayer adsorption capacity
	$K_{S}$ represents Sips equilibrium constant
	$m$ represents Sips heterogeneity exponent
	$C_{e}$ represents solute concentration (equilibrium)

Sips equilibrium constant
Sips heterogeneity exponent
adsorbed solute (equilibrium)
maximum monolayer adsorption capacity
solute concentration (equilibrium)

Computational tasks specializing nonlinear parameter estimation (Sips model)

linear parameter estimation (Freundlich isotherm)
nonlinear parameter estimation (Langmuir adsorption model)

Further items linking to nonlinear parameter estimation (Sips model)

Item	Property
Sips isotherm model	used by

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