Nonlinear parameter estimation (Sips model)

nonlinear estimation of Sips isotherm parameters

Description

This task performs nonlinear parameter estimation using adsorption equilibrium data. The objective is to determine the Sips maximum adsorption capacity, the Sips equilibrium constant, and the Sips heterogeneity exponent by fitting the nonlinear Sips equation directly to measured solute concentrations and adsorbed amounts. The nonlinear approach preserves the combined Langmuir-Freundlich behavior of the model and avoids distortions introduced by linearization. The results characterize both the adsorption affinity and the degree of surface heterogeneity governing the adsorption process.

Contained entities

maximum monolayer adsorption capacity		output
solute concentration (equilibrium)		input
adsorbed solute (equilibrium)		input
Sips equilibrium constant		output
Sips heterogeneity exponent		output
Sips equation	$q_{e} = q_{m} \frac{K_{S} C_{e}^{m}}{1 + K_{S} C_{e}^{m}}$
	$q_{e}$ represents adsorbed solute (equilibrium)
	$q_{m}$ represents maximum monolayer adsorption capacity
	$K_{S}$ represents Sips equilibrium constant
	$m$ represents Sips heterogeneity exponent
	$C_{e}$ represents solute concentration (equilibrium)

Specializations

nonlinear parameter estimation (Langmuir adsorption model), linear parameter estimation (Freundlich isotherm)

Further links

Item	Property
Sips isotherm model	used by

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