Nonlinear parameter estimation (Redlich-Peterson model)

nonlinear estimation of Redlich-Peterson model parameters

Named after

Description

This task performs nonlinear parameter estimation using experimental adsorption equilibrium data. The objective is to determine the Redlich-Peterson constant, coefficient, and exponent by directly fitting the nonlinear Redlich-Peterson equation to measured solute concentration and adsorbed amount data. Nonlinear regression preserves the full hybrid functional form, allowing the model to transition smoothly between Langmuir-like and Freundlich-like behavior. The resulting parameters quantify adsorption affinity, heterogeneity, and the degree of deviation from ideal monolayer adsorption.

Contained entities

Redlich-Peterson coefficient		output
adsorbed solute (equilibrium)		input
Redlich-Peterson exponent constraint	$0 \leq β \leq 1$	constraint
	$β$ represents Redlich-Peterson exponent

solute concentration (equilibrium)		input
Redlich-Peterson constant		output
Redlich-Peterson exponent		output
Redlich-Peterson equation	$q_{e} = \frac{A C_{e}}{1 + B C_{e}^{β}}$
	$q_{e}$ represents adsorbed solute (equilibrium)
	$C_{e}$ represents solute concentration (equilibrium)
	$A$ represents Redlich-Peterson constant
	$B$ represents Redlich-Peterson coefficient
	$β$ represents Redlich-Peterson exponent

Specializations

nonlinear parameter estimation (Langmuir adsorption model), linear parameter estimation (Henry's isotherm), linear parameter estimation (Freundlich isotherm)

Further links

Item	Property
Redlich-Peterson isotherm model	used by

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