nonlinear parameter estimation (Khan model)

Community: MathModDB

computational task	nonlinear task

Available identifiers

MaRDI QIDQ6821250 FDOQ6821250

nonlinear fitting of Khan isotherm parameters

Description

This task estimates the parameters of the Khan isotherm model by nonlinear regression using equilibrium adsorption data. Experimental measurements of equilibrium adsorbed amount and equilibrium concentration are fitted to the Khan equation to determine the maximum adsorption capacity, affinity constant, and heterogeneity exponent. The fitting process minimizes the deviation between observed and predicted adsorption values across the concentration range. The resulting parameters characterize adsorption capacity, surface affinity, and heterogeneity of the adsorbent. This task is commonly applied in adsorption studies of aqueous pollutants and organic solutes.

List of contained entities

Computational tasks specializing nonlinear parameter estimation (Khan model)

linear parameter estimation (Freundlich isotherm)
nonlinear parameter estimation (Langmuir adsorption model)

Further items linking to nonlinear parameter estimation (Khan model)

Item	Property
Khan isotherm model	used by

This page was built for task: nonlinear parameter estimation (Khan model)

Khan affinity parameter
Khan heterogeneity exponent
Khan heterogeneity exponent constraint	$a_{K} > 0$	constraint
	$a_{K}$ represents Khan heterogeneity exponent

Khan isotherm equation	$q_{e} = \frac{q_{S K} b_{K} C_{e}}{(1 + b_{K} C_{e})^{a_{K}}}$
	$q_{e}$ represents adsorbed solute (equilibrium)
	$C_{e}$ represents solute concentration (equilibrium)
	$q_{S K}$ represents Khan theoretical isotherm saturation capacity
	$b_{K}$ represents Khan affinity parameter
	$a_{K}$ represents Khan heterogeneity exponent

Khan theoretical isotherm saturation capacity
adsorbed solute (equilibrium)
solute concentration (equilibrium)