Phase transition upon solidification from a liquid state
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A criterion that allows one to predict a priori a mechanism (equilibrium or nonequilibrium) according to which the phase transition upon solidification of a melt from a liquid state will occur is obtained. The fundamental possibility of experimental determination of the kinetic constant and the energy of activation is shown on the basis of the phase-transition criterion obtained and the solution of the problem of sequential nonequilibrium crystallization.
Recommendations
- Solidification of binary alloys and nonequilibrium phase transitions
- Kinetic transition in the order-disorder transformation at a solid/liquid interface
- Metastable–solid phase diagrams derived from polymorphic solidification kinetics
- Non-equilibrium solidification of the molten metal droplets impacting on a solid surface
- scientific article; zbMATH DE number 2000316
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