Phase transition upon solidification from a liquid state

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A criterion that allows one to predict a priori a mechanism (equilibrium or nonequilibrium) according to which the phase transition upon solidification of a melt from a liquid state will occur is obtained. The fundamental possibility of experimental determination of the kinetic constant and the energy of activation is shown on the basis of the phase-transition criterion obtained and the solution of the problem of sequential nonequilibrium crystallization.











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