Elements of irreducible tensorial matrices generated by finite group with applications to ligand field Hamiltonians

DOI10.1007/BF01165126MaRDI QIDQ1360602zbMATH OpenFDO

Authors O. Diekmann

Publication date 15 November 1998

Published in Journal of Mathematical Chemistry (Search for Journal in Brave)

Full work available at URL https://doi.org/10.1007/BF01165126

zbMATH Keywords

crystallographic groupsfinite groupsirreducible representationsligand-field Hamiltoniansnormalized irreducible tensorial matricespoint symmetriestensor operators

Mathematics Subject Classification ID

Vector and tensor algebra, theory of invariants (15A72) Finite-dimensional groups and algebras motivated by physics and their representations (81R05) Molecular physics (81V55)

Review text

Finite symmetry groups are used to generate \(d\)-type ligand-field Hamiltonians. The irreducible representations of the involved group are employed to construct tensor operators of definite symmetry. Starting from a reference matrix, by elegant group theoretical methods the Hamiltonian is derived. This relation is substantial more efficient than previous techniques for evaluating matrix elements of octahedral and tetragonal \(d\)-type ligand-field Hamiltonians.

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• On the SU2 unit tensor
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Cited in

(4)

• Chromatic quasisymmetric functions of directed graphs
• Theoretical equations of Zeeman energy levels for distorted metal complexes with \(^5T_{2g}\) ground terms
• Applications of the S-function method for continuous groups to the classification of energy spectra in Ligand fields
• Group theoretical treatment of the Jan-Teller systems: T₁ (e t₂) coupling

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