A new coherent states approach to semiclassics which gives Scott's correction

DOI10.1007/s00220-003-0936-zzbMath1098.81040arXivmath-ph/0208044OpenAlexW3100157534WikidataQ59255785 ScholiaQ59255785MaRDI QIDQ1411065

Wolfgang L. Spitzer, Jan Philip Solovej

Publication date: 15 October 2003

Published in: Communications in Mathematical Physics (Search for Journal in Brave)

Full work available at URL: https://arxiv.org/abs/math-ph/0208044

zbMATH Keywords

Schrödinger operatorsnon-relativistic molecule Scott correctionsemiclassical eigenvalue-sum expansion

Mathematics Subject Classification ID

Atomic physics (81V45) Coherent states (81R30) Semiclassical techniques, including WKB and Maslov methods applied to problems in quantum theory (81Q20)

Related Items (20)

Two-term spectral asymptotics for the Dirichlet pseudo-relativistic kinetic energy operator on a bounded domain ⋮ The leading correction to the Thomas-Fermi model at finite temperature ⋮ Stability and semiclassics in self-generated fields ⋮ Sharp Weyl laws with singular potentials ⋮ Ground state energy of large atoms in a self-generated magnetic field ⋮ Two-term spectral asymptotics for the Dirichlet Laplacian in a Lipschitz domain ⋮ The Scott conjecture for large Coulomb systems: a review ⋮ Second order semiclassics with self-generated magnetic fields ⋮ Optimal semiclassical spectral asymptotics for differential operators with non-smooth coefficients ⋮ Scott correction for large atoms and molecules in a self-generated magnetic field ⋮ The magnetic Scott correction for relativistic matter at criticality ⋮ The ground state energy of heavy atoms: Relativistic lowering of the leading energy correction ⋮ Asymptotics for two-dimensional atoms ⋮ Semi-classical analysis of the Laplace operator with Robin boundary conditions ⋮ Spectral properties of the Dirichlet operator $\sum _{i=1}^{d}(-\partial _i^2)^{s}$∑i=1d(−∂i2)s on domains in d-dimensional Euclidean space ⋮ Semiclassical asymptotics for a class of singular Schrödinger operators ⋮ Relativistic Scott correction for atoms and molecules ⋮ The Scott correction in Dirac-Fock theory ⋮ Asymptotic shape optimization for Riesz means of the Dirichlet Laplacian over convex domains ⋮ Relativistic Scott correction in self-generated magnetic fields

Cites Work

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• An atomic energy lower bound that agrees with Scott's correction
• Sharp constants in the Hardy-Littlewood-Sobolev and related inequalities
• A proof of Scott's conjecture for ions
• Quantum coherent operators: A generalization of coherent states
• The Thomas-Fermi theory of atoms, molecules and solids
• On the leading energy correction for the statistical model of the atom: Interacting case
• Asymptotics of the ground state energies of large Coulomb systems
• On the asymptotic exactness of Thomas-Fermi theory in the thermodynamic limit
• On the energy of a large atom
• Thomas-fermi and related theories of atoms and molecules

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