General topics in linear spectral theory for PDEs (35P05) PDEs in connection with quantum mechanics (35Q40) Closed and approximate solutions to the Schrödinger, Dirac, Klein-Gordon and other equations of quantum mechanics (81Q05) Perturbation theories for operators and differential equations in quantum theory (81Q15) Covariant wave equations in quantum theory, relativistic quantum mechanics (81R20) Atomic physics (81V45) Molecular physics (81V55) Fermionic systems in quantum theory (81V74)
Abstract: We give the first derivation of the Scott correction in the large- expansion of the energy of an atom in Dirac-Fock theory without projections.
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- scientific article; zbMATH DE number 431794
Cites work
- A CORRELATION ESTIMATE WITH APPLICATIONS TO QUANTUM SYSTEMS WITH COULOMB INTERACTIONS
- A new coherent states approach to semiclassics which gives Scott's correction
- A proof of Scott's conjecture for ions
- Accuracy of mean field approximations for atoms and molecules
- An atomic energy lower bound that agrees with Scott's correction
- Analysis.
- Aperiodicity of the Hamiltonian flow in the Thomas-Fermi potential
- Asymptotics of the ground state energies of large Coulomb systems
- Asymptotics of the ground state energy of heavy molecules in a strong magnetic field. I
- Asymptotics of the ground state energy of heavy molecules in a strong magnetic field. II
- Characterization and uniqueness of distinguished self-adjoint extensions of Dirac operators
- Dirac operations with strongly singular potentials. Distinguished self- adjoint extensions constructed with a spectral gap theorem and cut-off potentials
- Distinguished self-adjoint extension of the two-body Dirac operator with Coulomb interaction
- Domains for Dirac-Coulomb min-max levels
- Eigenvalues and eigenfunctions of ordinary differential operators
- Error bound for the Hartree-Fock energy of atoms and molecules
- Existence of a stable polarized vacuum in the Bogoliubov-Dirac-Fock approximation
- Existence of atoms and molecules in the mean-field approximation of no-photon quantum electrodynamics
- Generalized Hartree-Fock theory and the Hubbard model
- Holomorphic families of Dirac operators
- scientific article; zbMATH DE number 3533409 (Why is no real title available?)
- scientific article; zbMATH DE number 1019185 (Why is no real title available?)
- scientific article; zbMATH DE number 1984596 (Why is no real title available?)
- scientific article; zbMATH DE number 852127 (Why is no real title available?)
- scientific article; zbMATH DE number 2212219 (Why is no real title available?)
- Lower bounds on the moduli of three-dimensional Coulomb-Dirac operators via fractional Laplacians with applications
- Nonrelativistic limit of the Dirac-Fock equations
- On the Dirac and Schwinger corrections to the ground-state energy of an atom
- On the eigenvalues of operators with gaps. Application to Dirac operators
- On the energy of a large atom
- On the interaction of two electrons
- On the leading correction of the Thomas-Fermi model: Lower bound
- On the leading energy correction for the statistical model of the atom: Interacting case
- On the stability of the relativistic electron-positron field
- Optimal upper bound for the correlation energy of a Fermi gas in the mean-field regime
- Proof of the ionization conjecture in a reduced Hartree-Fock model
- Relativistic Scott correction for atoms and molecules
- Self-adjoint extensions of Dirac operators with Coulomb type singularity
- Self-adjointness and invariance of the essential spectrum for Dirac operators defined as quadratic forms
- Self-consistent solution for the polarized vacuum in a no-photon QED model
- Solutions of the Dirac-Fock equations and the energy of the electron-positron field
- Solutions of the Dirac-Fock equations for atoms and molecules
- Solutions of the Dirac-Fock equations without projector.
- Spectral properties of Dirac operators with singular potentials
- Strict Positivity of a Relativistic Hamiltonian Due to Brown and Ravenhall
- The density in a one-dimensional potential
- The density in a three-dimensional radial potential
- The eigenvalue sum for a one-dimensional potential
- The energy of heavy atoms according to Brown and Ravenhall: the Scott correction
- The ground state energy of heavy atoms: Relativistic lowering of the leading energy correction
- The ground state energy of heavy atoms: the leading correction
- The ground-state energy of heavy atoms according to Brown and Ravenhall: absence of relativistic effects in leading order
- The large-Z Behavior of pseudorelativistic atoms
- The mean-field approximation in quantum electrodynamics: The no-photon case
- The semi-classical limit of large fermionic systems
- The Thomas-Fermi theory of atoms, molecules and solids
- Thomas-fermi and related theories of atoms and molecules
- Two-time Green's function method in quantum electrodynamics of high-\(Z\) few-electron atoms
- Variational methods in relativistic quantum mechanics
Cited in
(9)- Proof of the strong Scott conjecture for heavy atoms: the furry picture
- The Scott conjecture for large Coulomb systems: a review
- scientific article; zbMATH DE number 431794 (Why is no real title available?)
- The magnetic Scott correction for relativistic matter at criticality
- On the Hellmann-Feynman theorem and the corrections to the energy in the Rayleigh-Schrödinger perturbation theory
- A rigorous justification of the Mittleman's approach to the Dirac-Fock model
- A new definition of the Dirac-Fock ground state
- The ground state energy of heavy atoms: leading and subleading asymptotics
- The energy of heavy atoms according to Brown and Ravenhall: the Scott correction
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