The energy of heavy atoms according to Brown and Ravenhall: the Scott correction

MaRDI QIDQ845267zbMATH OpenFDO

Authors R. L. Frank, S. Warzel, Heinz Siedentop

Publication date 27 January 2010

Published in Documenta Mathematica (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/0805.4441, https://eudml.org/doc/223915, http://www.emis.de/journals/DMJDMV/vol-14/17.html

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zbMATH Keywords

hydrogen atomBrown-Ravenhall operatorSobolev inequalityground-state energyScott correctionThomas-Fermi modelheavy atomsChandrasekhar modelrelativistic atomSchrödinger many-particle operator

Mathematics Subject Classification ID

PDEs in connection with quantum mechanics (35Q40) Applications of functional analysis in quantum physics (46N50) Applications of operator theory in the physical sciences (47N50) Atomic physics (81V45) Molecular physics (81V55)

Abstract: We consider relativistic many-particle operators which - according to Brown and Ravenhall - describe the electronic states of heavy atoms. Their ground state energy is investigated in the limit of large nuclear charge and velocity of light. We show that the leading quasi-classical behavior given by the Thomas-Fermi theory is raised by a subleading correction, the Scott correction. Our result is valid for the maximal range of coupling constants, including the critical one. As a technical tool, a Sobolev-Gagliardo-Nirenberg-type inequality is established for the critical atomic Brown-Ravenhall operator. Moreover, we prove sharp upper and lower bound on the eigenvalues of the hydrogenic Brown-Ravenhall operator up to and including the critical coupling constant.

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Cited in

(13)

• BORN–OPPENHEIMER APPROXIMATION FOR THE BROWN–RAVENHALL EQUATION
• The ground state energy of heavy atoms: the leading correction
• A simple proof of Hardy-Lieb-Thirring inequalities
• Proof of the strong Scott conjecture for heavy atoms: the furry picture
• The magnetic Scott correction for relativistic matter at criticality
• The ground state energy of heavy atoms: Relativistic lowering of the leading energy correction
• The Scott conjecture for large Coulomb systems: a review
• A statistical theory of heavy atoms: asymptotic behavior of the energy and stability of matter
• The ground-state energy of heavy atoms according to Brown and Ravenhall: absence of relativistic effects in leading order
• Relativistic Scott correction for atoms and molecules
• The Scott correction in Dirac-Fock theory
• Scott correction for large atoms and molecules in a self-generated magnetic field
• The atomic density on the Thomas-Fermi length scale for the Chandrasekhar Hamiltonian

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