General considerations on the finite-size corrections for Coulomb systems in the Debye-Hückel regime
From MaRDI portal
(Redirected from Publication:1777945)
Abstract: We study the statistical mechanics of classical Coulomb systems in a low coupling regime (Debye-Huckel regime) in a confined geometry with Dirichlet boundary conditions. We use a method recently developed by the authors which relates the grand partition function of a Coulomb system in a confined geometry with a certain regularization of the determinant of the Laplacian on that geometry with Dirichlet boundary conditions. We study several examples of confining geometry in two and three dimensions and semi-confined geometries where the system is confined only in one or two directions of the space. We also generalize the method to study systems confined in arbitrary geometries with smooth boundary. We find a relation between the expansion for small argument of the heat kernel of the Laplacian and the large-size expansion of the grand potential of the Coulomb system. This allow us to find the finite-size expansion of the grand potential of the system in general. We recover known results for the bulk grand potential (in two and three dimensions) and the surface tension (for two dimensional systems). We find the surface tension for three dimensional systems. For two dimensional systems our general calculation of the finite-size expansion gives a proof of the existence a universal logarithmic finite-size correction predicted some time ago, at least in the low coupling regime. For three dimensional systems we obtain a prediction for the perimeter correction to the grand potential of a confined system.
Recommendations
- Finite-size corrections for Coulomb systems in the Debye–Hückel regime
- Coulomb systems seen as critical systems: Ideal conductor boundaries.
- Universality in some classical Coulomb systems of restricted dimension.
- Coulomb systems seen as critical systems: Finite-size effects in two dimensions
- Two-dimensional Coulomb systems in a disk with ideal dielectric boundaries.
Cites work
- A sum rule for the two-dimensional two-component plasma
- Can One Hear the Shape of a Drum?
- Classical Coulomb systems: Screening and correlations revisited.
- Coulomb systems seen as critical systems: Finite-size effects in two dimensions
- Coulomb systems seen as critical systems: Ideal conductor boundaries.
- Coulomb systems with ideal dielectric boundaries: Free fermion point and universality.
- Debye-Hückel theory for charge symmetric Coulomb systems
- Density correlations in the two-dimensional Coulomb gas
- Exact finite-size study of the 2D OCP at \(\Gamma=4\) and \(\Gamma=6\)
- Finite-size corrections for Coulomb systems in the Debye–Hückel regime
- scientific article; zbMATH DE number 3863589 (Why is no real title available?)
- scientific article; zbMATH DE number 3321874 (Why is no real title available?)
- On potential and field fluctuations in classical charged systems
- Spectral functions, special functions and the Selberg zeta function
- Surface tension for the two-component plasma at \(\Gamma=2\) near an interface
- Surface tension of a metal-electrolyte boundary: Exactly solvable model
- The sixth-moment sum rule for the pair correlations of the two-dimensional one-component plasma: Exact result
- The two-dimensional Coulomb gas on a sphere: Exact results
- Thermodynamic properties of the two-dimensional two-component plasma
- Two-dimensional Coulomb systems in a disk with ideal dielectric boundaries.
- Universal finite-size effects in the two-dimensional asymmetric Coulomb gas on a sphere
- Universality in some classical Coulomb systems of restricted dimension.
Cited in
(6)- Finite-size corrections for Coulomb systems in the Debye–Hückel regime
- ‘Screening’ of universal van der Waals–Casimir terms by Coulomb gases in a fully finite two-dimensional geometry
- Hartree corrections in a mean-field limit for fermions with Coulomb interaction
- Pressure of Coulomb systems with volume-dependent long-range potentials
- Microscopic calculation of the dielectric susceptibility tensor for Coulomb fluids. II
- Debye-Hückel theory for charge symmetric Coulomb systems
This page was built for publication: General considerations on the finite-size corrections for Coulomb systems in the Debye-Hückel regime
Report a bug (only for logged in users!)Click here to report a bug for this page (MaRDI item Q1777945)
