Orthogonality of fluxes in general nonlinear reaction networks

DOI10.3934/DCDSS.2020346zbMATH Open1454.82031arXiv1912.06436OpenAlexW2995047812MaRDI QIDQ1995410FDOQ1995410

D. R. Michiel Renger, Johannes Zimmer

Publication date: 23 February 2021

Published in: Discrete and Continuous Dynamical Systems. Series S (Search for Journal in Brave)

Abstract: We consider the chemical reaction networks and study currents in these systems. Reviewing recent decomposition of rate functionals from large deviation theory for Markov processes, we adapt these results for reaction networks. In particular, we state a suitable generalisation of orthogonality of forces in these systems, and derive an inequality that bounds the free energy loss and Fisher information by the rate functional.

Full work available at URL: https://arxiv.org/abs/1912.06436

zbMATH Keywords

orthogonalitylarge deviationschemical reactions

Mathematics Subject Classification ID

Continuous-time Markov processes on discrete state spaces (60J27) Stochastic methods (Fokker-Planck, Langevin, etc.) applied to problems in time-dependent statistical mechanics (82C31) Irreversible thermodynamics, including Onsager-Machlup theory (82C35)

Cites Work

• On the relation between gradient flows and the large-deviation principle, with applications to Markov chains and diffusion
• Solutions of ordinary differential equations as limits of pure jump markov processes
• Fluctuations and Irreversible Processes
• Large deviations and gradient flows
• Non-equilibrium Thermodynamical Principles for Chemical Reactions with Mass-Action Kinetics
• Large deviations of jump process fluxes
• An inequality connecting entropy distance, Fisher information and large deviations
• Canonical structure and orthogonality of forces and currents in irreversible Markov chains
• Flux large deviations of independent and reacting particle systems, with implications for macroscopic fluctuation theory

Cited In (7)

• Non-reversible processes: GENERIC, hypocoercivity and fluctuations
• Variational structures beyond gradient flows: a macroscopic fluctuation-theory perspective
• GENERIC framework for reactive fluid flows
• Jump processes as generalized gradient flows
• Dynamical phase transitions for flows on finite graphs
• Fast reaction limits via \(\Gamma\)-convergence of the flux rate functional
• Anisothermal chemical reactions: Onsager–Machlup and macroscopic fluctuation theory

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