Orthogonality of fluxes in general nonlinear reaction networks

DOI10.3934/DCDSS.2020346MaRDI QIDQ1995410zbMATH OpenOpenAlexFDO

Authors Johannes Zimmer, D. R. Michiel Renger

Publication date 23 February 2021

Published in Discrete and Continuous Dynamical Systems. Series S (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/1912.06436

zbMATH Keywords

orthogonalitylarge deviationschemical reactions

Mathematics Subject Classification ID

Continuous-time Markov processes on discrete state spaces (60J27) Stochastic methods (Fokker-Planck, Langevin, etc.) applied to problems in time-dependent statistical mechanics (82C31) Irreversible thermodynamics, including Onsager-Machlup theory (82C35)

Abstract: We consider the chemical reaction networks and study currents in these systems. Reviewing recent decomposition of rate functionals from large deviation theory for Markov processes, we adapt these results for reaction networks. In particular, we state a suitable generalisation of orthogonality of forces in these systems, and derive an inequality that bounds the free energy loss and Fisher information by the rate functional.

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Cites work

• An inequality connecting entropy distance, Fisher information and large deviations
• Canonical structure and orthogonality of forces and currents in irreversible Markov chains
• Fluctuations and Irreversible Processes
• Flux large deviations of independent and reacting particle systems, with implications for macroscopic fluctuation theory
• Large deviations and gradient flows
• Large deviations of jump process fluxes
• Non-equilibrium thermodynamical principles for chemical reactions with mass-action kinetics
• On the relation between gradient flows and the large-deviation principle, with applications to Markov chains and diffusion
• Solutions of ordinary differential equations as limits of pure jump markov processes

Cited in

(7)

• GENERIC framework for reactive fluid flows
• Dynamical phase transitions for flows on finite graphs
• Non-reversible processes: GENERIC, hypocoercivity and fluctuations
• Anisothermal chemical reactions: Onsager-Machlup and macroscopic fluctuation theory
• Jump processes as generalized gradient flows
• Fast reaction limits via \(\Gamma\)-convergence of the flux rate functional
• Variational structures beyond gradient flows: a macroscopic fluctuation-theory perspective

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