On the geometry of chemical reaction networks: Lyapunov function and large deviations

DOI10.1007/S10955-018-2035-8zbMATH Open1401.60042arXiv1710.07240OpenAlexW3101874238WikidataQ129931669 ScholiaQ129931669MaRDI QIDQ1785575FDOQ1785575

Authors: Andrea Agazzi, Amir Dembo, Jean-Pierre Eckmann 

Publication date: 1 October 2018

Published in: Journal of Statistical Physics (Search for Journal in Brave)

Abstract: In an earlier paper, we proved the validity of large deviations theory for the particle approximation of quite general chemical reaction networks (CRNs). In this paper, we extend its scope and present a more geometric insight into the mechanism of that proof, exploiting the notion of spherical image of the reaction polytope. This allows to view the asymptotic behavior of the vector field describing the mass-action dynamics of chemical reactions as the result of an interaction between the faces of this polytope in different dimensions. We also illustrate some local aspects of the problem in a discussion of Wentzell-Freidlin (WF) theory, together with some examples.

Full work available at URL: https://arxiv.org/abs/1710.07240

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zbMATH Keywords

dynamical systemslarge deviationstropical geometrymolecular networks

Mathematics Subject Classification ID

Large deviations (60F10) Chemical kinetics in thermodynamics and heat transfer (80A30) Classical flows, reactions, etc. in chemistry (92E20)

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Cited In (10)

• Orthogonality of fluxes in general nonlinear reaction networks
• Univalent positive polynomial maps and the equilibrium state of chemical networks of reversible binding reactions
• Tier structure of strongly endotactic reaction networks
• Anisothermal chemical reactions: Onsager-Machlup and macroscopic fluctuation theory
• Prevalence of deficiency-zero reaction networks in an Erdős-Rényi framework
• Large deviations of Markov chains with multiple time-scales
• Detailed balance, local detailed balance, and global potential for stochastic chemical reaction networks
• Large deviations theory for Markov jump models of chemical reaction networks
• Large deviations for Markov jump processes with uniformly diminishing rates
• Modeling of chemical reaction systems with detailed balance using gradient structures

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