Large deviations theory for Markov jump models of chemical reaction networks
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Publication:1661572
Abstract: We prove a sample path Large Deviation Principle (LDP) for a class of jump processes whose rates are not uniformly Lipschitz continuous in phase space. Building on it we further establish the corresponding Wentzell-Freidlin (W-F) (infinite time horizon) asymptotic theory. These results apply to jump Markov processes that model the dynamics of chemical reaction networks under mass action kinetics, on a microscopic scale. We provide natural sufficient topological conditions for the applicability of our LDP and W-F results. This then justifies the computation of non-equilibrium potential and exponential transition time estimates between different attractors in the large volume limit, for systems that are beyond the reach of standard chemical reaction network theory.
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Cited in
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- Phase reduction of stochastic biochemical oscillators
- Revisit of macroscopic dynamics for some non-equilibrium chemical reactions from a Hamiltonian viewpoint
- Results on stochastic reaction networks with non-mass action kinetics
- Stationary distributions and condensation in autocatalytic reaction networks
- Detailed balance, local detailed balance, and global potential for stochastic chemical reaction networks
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- Stochastically modeled weakly reversible reaction networks with a single linkage class
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- Fast reaction limits via \(\Gamma\)-convergence of the flux rate functional
- Modeling of chemical reaction systems with detailed balance using gradient structures
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