Large deviations theory for Markov jump models of chemical reaction networks
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Publication:1661572
DOI10.1214/17-AAP1344zbMATH Open1410.60034arXiv1701.02126OpenAlexW2962734224WikidataQ129738399 ScholiaQ129738399MaRDI QIDQ1661572FDOQ1661572
Andrea Agazzi, Jean-Pierre Eckmann, Amir Dembo
Publication date: 16 August 2018
Published in: The Annals of Applied Probability (Search for Journal in Brave)
Abstract: We prove a sample path Large Deviation Principle (LDP) for a class of jump processes whose rates are not uniformly Lipschitz continuous in phase space. Building on it we further establish the corresponding Wentzell-Freidlin (W-F) (infinite time horizon) asymptotic theory. These results apply to jump Markov processes that model the dynamics of chemical reaction networks under mass action kinetics, on a microscopic scale. We provide natural sufficient topological conditions for the applicability of our LDP and W-F results. This then justifies the computation of non-equilibrium potential and exponential transition time estimates between different attractors in the large volume limit, for systems that are beyond the reach of standard chemical reaction network theory.
Full work available at URL: https://arxiv.org/abs/1701.02126
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Cited In (22)
- Prevalence of deficiency-zero reaction networks in an Erdös–Rényi framework
- Stochastically modeled weakly reversible reaction networks with a single linkage class
- Stationary Distributions and Condensation in Autocatalytic Reaction Networks
- Revisit of macroscopic dynamics for some non-equilibrium chemical reactions from a Hamiltonian viewpoint
- Individual Molecules Dynamics in Reaction Network Models
- Adaptive aggregation of Markov chains: quantitative analysis of chemical reaction networks
- Many-server asymptotics for join-the-shortest-queue: large deviations and rare events
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- Large deviations for Markov jump processes with uniformly diminishing rates
- Fast reaction limits via \(\Gamma\)-convergence of the flux rate functional
- Modeling of chemical reaction systems with detailed balance using gradient structures
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