Global thermodynamics for heat conduction systems

DOI10.1007/S10955-019-02393-2zbMATH Open1431.82023arXiv1906.07022OpenAlexW2953326715WikidataQ127126678 ScholiaQ127126678MaRDI QIDQ2283147FDOQ2283147

Authors: Naoko Nakagawa, Shin-ichi Sasa 

Publication date: 30 December 2019

Published in: Journal of Statistical Physics (Search for Journal in Brave)

Abstract: We propose the concept of global temperature for spatially non-uniform heat conduction systems. With this novel quantity, we present an extended framework of thermodynamics for the whole system such that the fundamental relation of thermodynamics holds, which we call "global thermodynamics" for heat conduction systems. Associated with this global thermodynamics, we formulate a variational principle for determining thermodynamic properties of the liquid-gas phase coexistence in heat conduction, which corresponds to the natural extension of the Maxwell construction for equilibrium systems. We quantitatively predict that the temperature of the liquid-gas interface deviates from the equilibrium transition temperature. This result indicates that a super-cooled gas stably appears near the interface.

Full work available at URL: https://arxiv.org/abs/1906.07022

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zbMATH Keywords

heat conductionthermodynamicsliquid-gas transitionsuper-cooled gas

Mathematics Subject Classification ID

Exactly solvable models; Bethe ansatz (82B23) Critical phenomena in equilibrium statistical mechanics (82B27) Dynamic critical phenomena in statistical mechanics (82C27) Irreversible thermodynamics, including Onsager-Machlup theory (82C35)

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Cited In (3)

• Electric-field driven nonequilibrium phase transitions in AdS/CFT
• Simulations of transport in hard particle systems
• Soluciones globales para sistema isotérmico con fuente

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