Phase field modelling of surfactants in multi-phase flow
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Publication:2295753
DOI10.4171/IFB/429zbMATH Open1431.35255arXiv1810.12274OpenAlexW2996100013MaRDI QIDQ2295753FDOQ2295753
Authors: Oliver R. A. Dunbar, Kei Fong Lam, Björn Stinner 
Publication date: 14 February 2020
Published in: Interfaces and Free Boundaries (Search for Journal in Brave)
Abstract: A diffuse interface model for surfactants in multi-phase flow with three or more fluids is derived. A system of Cahn-Hilliard equations is coupled with a Navier-Stokes system and an advection-diffusion equation for the surfactant ensuring thermodynamic consistency. By an asymptotic analysis the model can be related to a moving boundary problem in the sharp interface limit, which is derived from first principles. Results from numerical simulations support the theoretical findings. The main novelties are centred around the conditions in the triple junctions where three fluids meet. Specifically the case of local chemical equilibrium with respect to the surfactant is considered, which allows for interfacial surfactant flow through the triple junctions.
Full work available at URL: https://arxiv.org/abs/1810.12274
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Asymptotic expansions of solutions to PDEs (35C20) PDEs on manifolds (35R01) Moving boundary problems for PDEs (35R37) Capillarity (surface tension) for incompressible viscous fluids (76D45) Three or more component flows (76T30)
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