Mathematical conception of ``phenomenological equilibrium thermodynamics
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Publication:2344121
DOI10.1134/S1061920811040066zbMATH Open1326.82009arXiv1111.6106OpenAlexW2055600665MaRDI QIDQ2344121FDOQ2344121
Authors: V. P. Maslov
Publication date: 12 May 2015
Published in: Russian Journal of Mathematical Physics (Search for Journal in Brave)
Abstract: In the paper, the principal aspects of the mathematical theory of equilibrium thermodynamics are distinguished. It is proved that the points of degeneration of a Bose gas of fractal dimension in the momentum space coincide with critical points or real gases, whereas the jumps of critical indices and the Maxwell rule are related to the tunnel generalization of thermodynamics. Semiclassical methods are considered for the tunnel generalization of thermodynamics and also for the second and ultrasecond quantization (operators of creation and annihilation of pairs). To every pure gas there corresponds a new critical point of the limit negative pressure below which the liquid passes to a dispersed state (a foam). Relations for critical points of a homogeneous mixture of pure gases are given in dependence on the concentration of gases.
Full work available at URL: https://arxiv.org/abs/1111.6106
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