Perturbation theory by the moment method and point-group symmetry

DOI10.1007/S10910-014-0457-3MaRDI QIDQ2353555zbMATH OpenOpenAlexFDO

Authors Francisco M. Fernández

Publication date 15 July 2015

Published in Journal of Mathematical Chemistry (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/1409.4120

Mathematics Subject Classification ID

Ordinary representations and characters (20C15) Other geometric groups, including crystallographic groups (20H15) Perturbation theories for operators and differential equations in quantum theory (81Q15) Finite-dimensional groups and algebras motivated by physics and their representations (81R05) Quantum equilibrium statistical mechanics (general) (82B10)

Abstract: We analyze earlier applications of perturbation theory by the moment method (also called inner product method) to anharmonic oscillators. For concreteness we focus on two-dimensional models with symmetry $C_{4v}$ and $C_{2v}$ and reveal the reason why some of those earlier treatments proved unsuitable for the calculation of the perturbation corrections for some excited states. Point-group symmetry enables one to predict which states require special treatment.

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Cites work

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• The perturbed three-dimensional oscillator
• The perturbed two-dimensional oscillator

Cited in

(2)

• Unitary transformations of a family of two-dimensional anharmonic oscillators
• On the symmetry of three identical interacting particles in a one-dimensional box

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