The penetrable-sphere fluid in the high-temperature, high-density limit

DOI10.1016/J.PHYSLETA.2004.02.039MaRDI QIDQ2383232zbMATH OpenOpenAlexFDO

Authors L. Acedo, Andres Santos

Publication date 8 October 2007

Published in Physics Letters. A (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/cond-mat/0308628

zbMATH Keywords

fluid-solid phase transitionpenetrable-sphere modelsoft interactionsspinodal instability

Mathematics Subject Classification ID

Statistical mechanics of liquids (82D15)

Abstract: We consider a fluid of $d$-dimensional spherical particles interacting via a pair potential $phi(r)$ which takes a finite value $epsilon$ if the two spheres are overlapped ($r<sigma$) and 0 otherwise. This penetrable-sphere model has been proposed to describe the effective interaction of micelles in a solvent. We derive the structural and thermodynamic functions in the limit where the reduced temperature $k_{B}T/epsilon$ and density $hosigm{a}^d$ tend to infinity, their ratio being kept finite. The fluid exhibits a spinodal instability at a certain maximum scaled density where the correlation length diverges and a crystalline phase appears, even in the one-dimensional model. By using a simple free-volume theory for the solid phase of the model, the fluid-solid phase transition is located.

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Cites work

• scientific article; zbMATH DE number 1332581 (Why is no real title available?)
• Derivation of the classical theory of correlations in fluids by means of functional differentiation
• Phase separation of penetrable core mixtures

Cited in

(7)

• Hard-sphere fluids with chemical self-potentials
• One-dimensional fluids with positive potentials
• Structure and phase behaviors of confined two penetrable soft spheres
• Characterization of the structural collapse undergone by an unstable system of ultrasoft particles
• Thermodynamics of a fluid system interacting via a ``Mexican Hat-pair potential
• Solid-fluid transition of two- or three-dimensional systems with infinite-range interaction
• Molecular fluids at high dimensionality

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