Hard-sphere fluids with chemical self-potentials
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Publication:3580892
Abstract: Existence, uniqueness and stability of solutions is studied for a set of nonlinear fixed point equations which define self-consistent hydrostatic equilibria of a classical continuum fluid that is confined inside a container and in contact with either a heat and a matter reservoir, or just a heat reservoir. The local thermodynamics is furnished by the statistical mechanics of a system of hard balls, in the approximation of Carnahan-Starling. The fluid's local chemical potential per particle at is the sum of the matter reservoir's contribution and a self contribution which is computed by convoluting the fluid density distribution with a van der Waals, a Yukawa, or a Newton kernel. We prove the existence of a grand canonical phase transition, and a petit canonical phase transition which is embedded in the former.
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Cited in
(3)- On the Schrödinger spectrum of a Hydrogen atom with electrostatic Bopp-Landé-Thomas-Podolsky interaction between electron and proton
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