Delay-controlled reactions

DOI10.1016/J.PHYSLETA.2003.12.045MaRDI QIDQ2383306zbMATH OpenOpenAlexFDO

Authors Knud Zabrocki, S. Trimper

Publication date 8 October 2007

Published in Physics Letters. A (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/cond-mat/0303067

Mathematics Subject Classification ID

Chemical kinetics in thermodynamics and heat transfer (80A30)

Abstract: When the entities undergoing a chemical reaction are not available simultaneously, the classical rate equation of a reaction or, alternatively for the evolution of a population, should be extended by including non-Markovian memory effects. We consider the two cases of an external feedback, realized by fixed functions and an internal feedback originated in a self-organized manner by the relevant concentration itself. Whereas in the first case the fixed points are not changed, although the dynamical process is altered, the second case offers a complete new behaviour, characterized by the existence of a time persistent solution. Due to the feedback the reaction may lead to a finite concentration in the stationary limit even in case of a single-species pair annihilation $A+Ao0$ process. We argue that the different cases are similar to a coupling of additive or multiplicative noises in stochastic processes.

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Cites work

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• Diffusion and reactions in fractals and disordered systems
• Exactly solvable model of reactions on a random catalytic chain
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