On oscillations and noise in multicomponent adsorption: the nature of multiple stationary states

DOI10.1155/2019/7687643MaRDI QIDQ2425105zbMATH OpenOpenAlexFDO

Authors Olga M. Jakšić, Zoran Jakšić, Milena B. Rašljić, Ljiljana Kolar-Anić

Publication date 26 June 2019

Published in Advances in Mathematical Physics (Search for Journal in Brave)

Copyright license Creative Commons Attribution 4.0 International

Full work available at URL https://doi.org/10.1155/2019/7687643

zbMATH Keywords

multicomponent adsorptionoscillationstochastic chemical master equation

Mathematics Subject Classification ID

Oscillation theory, zeros, disconjugacy and comparison theory for ordinary differential equations (34C10) Stationary solutions of functional-differential equations (34K21) Stationary stochastic processes (60G10) Chemically reacting flows (80A32)

Review text

Summary: Starting from the fact that monocomponent adsorption, whether modeled by Lagergren or nonlinear Riccati equations, does not sustain oscillations. We speculate about the nature of multiple steady state states in multicomponent adsorption with second-order kinetics and about the possibility that multicomponent adsorption might exhibit oscillating behavior, in order to provide a tool for better discerning possible oscillations from inevitable fluctuations in experimental results or a tool for a better control of adsorption process far from equilibrium. We perform an analysis of stability of binary adsorption with second-order kinetics in multiple ways. We address perturbations around the steady state analytically, first in a classical way, then by introducing Langevin forces and analyzing the reaction flux and cross-correlations, then by applying the stochastic chemical master equation approach, and finally, numerically, by using stochastic simulation algorithms. Our results show that stationary states in this model are stable nodes. Hence, experimental results with purported oscillations in response should be addressed from the point of view of fluctuations and noise analysis.

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Cites work

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• Handbook of stochastic methods for physics, chemistry and natural sciences.
• scientific article; zbMATH DE number 5070674 (Why is no real title available?)

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(3)

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Describes a project that uses

Uses Software

• Matlab
• ADmoND

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