The rotation-vibration coupling in diatomic molecules.

DOI10.1103/PHYSREV.45.98MaRDI QIDQ2618705zbMATH OpenFDO

Authors C. L. Pekeris

Publication date 1934

Published in Physical Review, II. Series (Search for Journal in Brave)

Full work available at URL https://doi.org/10.1103/PHYSREV.45.98

Review text

Durchführung der Integration der \textit{Schrödinger}-Gleichung nach der Methode der Integraltransformation. Man erhält als radiale Differentialgleichung eine Gleichung, die in unklarer Form angeschrieben ist und wohl \[ \frac {d^2 F}{dz^2} + \left ( \frac {v+b+1}{z} -1 \right ) F=0 \] heißen soll. Die \textit{Laplace}\,sche Transformation \[ F(z)=\int e^{-zt} f(t) dt \] liefert die Lösung \[ F(z)=\frac {c}{2\pi i} \oint e^{-zt} t^{-(1+v)} (1+t)^{(b+v)} dt. \]

Cited in

(4)

• An analytical approach to the Schrödinger-Newton equations
• Path integral treatment of a linear combination of deformed diatomic molecule potentials
• A new conjecture for obtaining the energy spectra of the wave equations under solvable potentials
• Approximate non-relativistic s-wave energy spectra with non-polynomial potentials within the framework of the WKB approximation

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