Fluctuations of intensive quantities in statistical thermodynamics

DOI10.3390/E15114889zbMATH Open1349.82023OpenAlexW2118369605MaRDI QIDQ280693FDOQ280693

Authors Artur E. Ruuge

Publication date 10 May 2016

Published in Entropy (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/1309.4439

zbMATH Keywords

dualityfluctuationsquantizationthermodynamicsPauli problem

Mathematics Subject Classification ID

Statistical thermodynamics (82B30)

Abstract: In phenomenological thermodynamics, the canonical coordinates of a physical system split in pairs with each pair consisting of an extensive quantity and an intensive one. In the present paper, the quasi-thermodynamic fluctuation theory of a model system of a large number of oscillators is extended to statistical thermodynamics based on the idea to perceive the fluctuations of intensive variables as the fluctuations of specific extensive ones in a "thermodynamically dual" system. The extension is motivated by the symmetry of the problem in the context of an analogy with quantum mechanics which is stated in terms of a generalized Pauli problem for the thermodynamic fluctuations. The doubled Boltzmann constant divided by the number of particles plays a similar role to the Planck constant.

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Cited in

(7)

• A tropical analogue of the Pauli problem and a splitting of quasithermodynamics
• Table of stable chemical elements based on the ``intensity-compressibility factor diagram and on mean square fluctuations of energy and time
• EFFECTS OF SAMPLE-SPECIFIC VARIATIONS AND FLUCTUATIONS OF THERMAL OCCUPANCY ON FLUCTUATIONS OF THERMODYNAMIC QUANTITIES
• Thermodynamic theory of equilibrium fluctuations
• On the speed of fluctuations around thermodynamic equilibrium
• Integral fluctuation theorem for the housekeeping heat
• An asymptotics of the Pauli problem in thermodynamics

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