Virial theorem and hypervirial theorem in a spherical geometry

DOI10.1088/1751-8113/44/36/365306zbMATH Open1227.81263OpenAlexW2040964772MaRDI QIDQ3173039FDOQ3173039

Authors Yan Li, Fu-Lin Zhang, Jing-Ling Chen 

Publication date 10 October 2011

Published in Journal of Physics A: Mathematical and Theoretical (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/1012.5391

Mathematics Subject Classification ID

Closed and approximate solutions to the Schrödinger, Dirac, Klein-Gordon and other equations of quantum mechanics (81Q05) Atomic physics (81V45) Molecular physics (81V55)

Abstract: The Virial Theorem in the one- and two-dimensional spherical geometry are presented, in both classical and quantum mechanics. Choosing a special class of Hypervirial operators, the quantum Hypervirial relations in the spherical spaces are obtained. With the aid of the Hellmann-Feynman Theorem, these relations can be used to formulate a emph{perturbation theorem without wave functions}, corresponding to the Hypervirial-Hellmann-Feynman Theorem perturbation theorem of Euclidean geometry. The one-dimensional harmonic oscillator and two-dimensional Coulomb system in the spherical spaces are given as two sample examples to illustrate the perturbation method.

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• Canonical perturbation expansions to large order from classical hypervirial and Hellmann–Feynman theorems
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