The large-Z Behavior of pseudorelativistic atoms

DOI10.1063/1.1897645MaRDI QIDQ3438403zbMATH OpenOpenAlexFDO

Authors T.Østergaard Sørensen

Publication date 16 May 2007

Published in Journal of Mathematical Physics (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/math-ph/0408056

Mathematics Subject Classification ID

Atomic physics (81V45)

Abstract: In this paper we study the large-Z behaviour of the ground state energy of atoms with electrons having relativistic kinetic energy sqrt(p^2c^2+m^2c^4)-mc^2. We prove that to leading order in Z the energy is the same as in the non-relativistic case, given by (non-relativistic) Thomas-Fermi theory. For the problem to make sense, we keep the product Z*alpha fixed (here alpha is Sommerfeld's fine structure constant), and smaller than, or equal to, 2/pi, which means that as Z tends to infinity, alpha tends to zero.

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Cited in

(17)

• Ground state energy of large atoms in a self-generated magnetic field
• Green function estimates for relativistic stable processes in half-space-like open sets
• The ground state energy of heavy atoms: the leading correction
• Hartree-Fock theory for pseudorelativistic atoms
• New bounds on the maximum ionization of atoms
• The magnetic Scott correction for relativistic matter at criticality
• Bounds on diatomic molecules in a relativistic model
• The ground state energy of heavy atoms: Relativistic lowering of the leading energy correction
• The Scott conjecture for large Coulomb systems: a review
• The ground state of relativistic ions in the limit of high magnetic fields
• A statistical theory of heavy atoms: asymptotic behavior of the energy and stability of matter
• Relativistic Scott correction for atoms and molecules
• The Scott correction in Dirac-Fock theory
• RELATIVISTIC CORRECTIONS OF THE α²-ORDER FOR THE TOTAL ENERGY AND THE MINIMUM PRESSURE IN THE THOMAS–FERMI THEORY
• Sharp heat kernel estimates for relativistic stable processes in open sets
• The ground state energy of relativistic one-electron atoms according to Jansen and Heß
• The atomic density on the Thomas-Fermi length scale for the Chandrasekhar Hamiltonian

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