Variational treatment of the confined hydrogen atom with a moving nucleus
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Publication:3566485
DOI10.1088/0143-0807/31/3/018zbMATH Open1189.81272arXiv1009.2154OpenAlexW3123417685MaRDI QIDQ3566485FDOQ3566485
Authors: Francisco M. Fernández 
Publication date: 8 June 2010
Published in: European Journal of Physics (Search for Journal in Brave)
Abstract: We calculate the ground--state energy and other physical properties of the hydrogen atom inside a spherical box with an impenetrable wall. We apply the variational method and perturbation theory and compare both approximate results. We show that the total, kinetic and potential energies for the moving--nucleus model are greater than those for the case in which the nucleus is clamped at the box center.
Full work available at URL: https://arxiv.org/abs/1009.2154
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Closed and approximate solutions to the Schrödinger, Dirac, Klein-Gordon and other equations of quantum mechanics (81Q05) Atomic physics (81V45)
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- Perturbation theory for confined systems
- States of a hydrogen atom in an impenetrable cubic cavity
- The confined hydrogen atom with a moving nucleus
- The Kustaanheimo-Stiefel transformation applied to the hydrogen atom: using the constraint equation and resolving a wavefunction discrepancy
- Variational perturbation treatment of the confined hydrogen atom
- The confined hydrogen atom: a linear variational approach
- Spherically compressed helium atom described by perturbative and variational methods
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