Perturbation theory for confined systems

DOI10.1007/S10910-013-0252-6MaRDI QIDQ2441099zbMATH OpenOpenAlexFDO

Authors Francisco M. Fernández

Publication date 21 March 2014

Published in Journal of Mathematical Chemistry (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/1004.2508, http://hdl.handle.net/11336/5164

zbMATH Keywords

confined systemsHelium atomperturbation theory

Mathematics Subject Classification ID

Dynamic continuum models (systems of particles, etc.) in time-dependent statistical mechanics (82C21) Interacting particle systems in time-dependent statistical mechanics (82C22)

Abstract: We discuss the application of perturbation theory to a system of particles confined in a spherical box. A simple argument shows that the particles behave almost independently in sufficiently strong confinement. We choose the helium atom with a moving nucleus as a particular example and compare results of first order with those for the nucleus clamped at the center of the box. We provide a suitable explanation for some numerical results obtained recently by other authors.

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Cites work

• A highly accurate study of a helium atom under pressure
• scientific article; zbMATH DE number 1555992 (Why is no real title available?)
• The confined hydrogen atom with a moving nucleus
• The ground state energy of a helium atom under strong confinement

Cited in

(9)

• \(N\) identical particles under quantum confinement: a many-body dimensional perturbation theory approach.
• Monotonicity in confined system problems
• Perturbation theory for particle in a box
• Comment on: ``On the characteristic polynomial of an effective Hamiltonian
• The confined hydrogen atom with a moving nucleus
• Variational treatment of the confined hydrogen atom with a moving nucleus
• scientific article; zbMATH DE number 1014931 (Why is no real title available?)
• Perturbation theory for the one-dimensional trapping reaction
• Variational perturbation treatment of the confined hydrogen atom

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