A variational formula for the free energy of the partially directed polymer collapse

DOI10.1007/S10955-013-0748-2MaRDI QIDQ359570zbMATH OpenOpenAlexFDO

Authors Gia Bao Nguyen, Nicolas Pétrélis

Publication date 12 August 2013

Published in Journal of Statistical Physics (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/1211.0925

zbMATH Keywords

phase transitionpolymer collapsevariational formula

Mathematics Subject Classification ID

Random walks, random surfaces, lattice animals, etc. in equilibrium statistical mechanics (82B41) Critical phenomena in equilibrium statistical mechanics (82B27) Statistical mechanics of polymers (82D60)

Abstract: Long linear polymers in dilute solutions are known to undergo a collapse transition from a random coil (expand itself) to a compact ball (fold itself up) when the temperature is lowered, or the solvent quality deteriorates. A natural model for this phenomenon is a 1+1 dimensional self-interacting and partially directed self-avoiding walk. In this paper, we develop a new method to study the partition function of this model, from which we derive a variational formula for the free energy. This variational formula allows us to prove the existence of the collapse transition and to identify the critical temperature in a simple way. We also prove that the order of the collapse transition is 3/2.

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Cites work

• scientific article; zbMATH DE number 5819433 (Why is no real title available?)
• A collapse transition in a directed walk model
• A self-interacting partially directed walk subject to a force
• Distribution of some functionals of the integral of a random walk
• Families of prudent self-avoiding walks
• Lectures on random polymers
• Persistence probabilities and exponents
• Pinning and wetting transition for (1\(+\)1)-dimensional fields with Laplacian interaction
• The tricritical behavior of self-interacting partially directed walks

Cited in

(10)

• A collapse transition in a directed walk model
• Classical length-5 pattern-avoiding permutations
• Interacting partially directed self avoiding walk. From phase transition to the geometry of the collapsed phase
• Interacting partially directed self-avoiding walk: a probabilistic perspective
• Surface transition in the collapsed phase of a self-interacting walk adsorbed along a hard wall
• A sharp asymptotics of the partition function for the collapsed interacting partially directed self-avoiding walk
• A scaling theory of the collapse transition in geometric cluster models of polymers and vesicles
• \(1/d\)-expansions for the free energy of weakly embedded site animal models of branched polymers
• Generalized Poland-Scheraga denaturation model and two-dimensional renewal processes
• A shape theorem for the scaling limit of the IPDSAW at criticality

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