Ideal mixture approximation of cluster size distributions at low density
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Abstract: We consider an interacting particle system in continuous configuration space. The pair interaction has an attractive part. We show that, at low density, the system behaves approximately like an ideal mixture of clusters (droplets): we prove rigorous bounds (a) for the constrained free energy associated with a given cluster size distribution, considered as an order parameter, (b) for the free energy, obtained by minimising over the order parameter, and (c) for the minimising cluster size distributions. It is known that, under suitable assumptions, the ideal mixture has a transition from a gas phase to a condensed phase as the density is varied; our bounds hold both in the gas phase and in the coexistence region of the ideal mixture. The present paper improves our earlier results by taking into account the mixing entropy.
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Cites work
- scientific article; zbMATH DE number 3120653 (Why is no real title available?)
- A proof of crystallization in two dimensions
- Equilibrium distributions of physical clusters
- Large deviations for cluster size distributions in a continuous classical many-body system
- Mayer and virial series at low temperature
- Minimizing atomic configurations of short range pair potentials in two dimensions: crystallization in the Wulff shape
- Phase transitions for dilute particle systems with Lennard-Jones potential
- The Becker-Döring cluster equations: Basic properties and asymptotic behaviour of solutions
Cited in
(6)- Thermodynamics of a hierarchical mixture of cubes
- Clustering in interfering binary mixtures
- On the low-temperature behavior of the infinite-volume ideal Bose gas
- Cluster size distribution in a system of randomly spaced particles
- Large deviations for cluster size distributions in a continuous classical many-body system
- Overcomplete free energy functional for \(D\) = 1 particle systems with next neighbor interactions
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