A LAGUERRE POLYNOMIAL ORTHOGONALITY AND THE HYDROGEN ATOM

DOI10.1142/S0219530503000132MaRDI QIDQ4474587zbMATH OpenWikidataFDO

Authors Charles F. Dunkl

Publication date 12 July 2004

Published in Analysis and Applications (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/math-ph/0011021

zbMATH Keywords

Meixner polynomialsLaguerre functionsCoulomb potential

Mathematics Subject Classification ID

Orthogonal polynomials and functions of hypergeometric type (Jacobi, Laguerre, Hermite, Askey scheme, etc.) (33C45) PDEs in connection with quantum mechanics (35Q40) Atomic physics (81V45) Confluent hypergeometric functions, Whittaker functions, ({}_1F_1) (33C15)

Abstract: The radial part of the wave function of an electron in a Coulomb potential is the product of a Laguerre polynomial and an exponential with the variable scaled by a factor depending on the degree. This note presents an elementary proof of the orthogonality of wave functions with differing energy levels. It is also shown that this is the only other natural orthogonality for Laguerre polynomials. By expanding in terms of the usual Laguerre polynomial basis an analogous strange orthogonality is obtained for Meixner polynomials.

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Cites work

• Factorization of the radial Schrödinger equation of the hydrogen atom
• Strong asymptotics of Laguerre polynomials and information entropies of two-dimensional harmonic oscillator and one-dimensional Coulomb potentials
• Uniform asymptotic expansions for Meixner polynomials
• Upper limit of the discrete hydrogen-like wave functions: Expansion in the inverse principal quantum number n−1

Cited in

(13)

• Applications of non-orthogonal Laguerre function basis in helium atom
• Direct spreading measures of Laguerre polynomials
• The Dunkl-Coulomb problem in the plane
• Schrödinger and Dirac equations for the hydrogen atom, and Laguerre polynomials
• Wall crossing from Dirac zeromodes
• Laguerre semigroup and Dunkl operators
• scientific article; zbMATH DE number 811974 (Why is no real title available?)
• Euclidean Jordan algebras, hidden actions, and J-Kepler problems
• Generalized Kepler problems. I: Without magnetic charges
• Recurrence relations for generalized Laguerre polynomials
• Inverse momentum expectation values for hydrogenic systems
• Slepian spatial-spectral concentration on the ball
• Exactly solvable stochastic spectator

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