Induced-charge electro-osmosis

DOI10.1017/S0022112004009309MaRDI QIDQ4659652zbMATHOpenAlexWikidataFDO

Authors Todd M. Squires, Martin Z. Bazant

Publication date 21 March 2005

Published in Journal of Fluid Mechanics (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/physics/0304090

zbMATH Keywords

matched asymptotic expansionnonlinear electrokinetics

Mathematics Subject Classification ID

Magnetohydrodynamics and electrohydrodynamics (76W05)

Abstract: We describe the general phenomenon of `induced-charge electro-osmosis' (ICEO) -- the nonlinear electro-osmotic slip that occurs when an applied field acts on the ionic charge it {sl induces} around a polarizable surface. Motivated by a simple physical picture, we calculate ICEO flows around conducting cylinders in steady (DC), oscillatory (AC), and suddenly-applied electric fields. This picture, and these systems, represent perhaps the clearest example of nonlinear electrokinetic phenomena. We complement and verify this physically-motivated approach using a matched asymptotic expansion to the electrokinetic equations in the thin double-layer and low potential limits. ICEO slip velocities vary like $u_{s}propto{E}_0^{2}L$, where $E_0$ is the field strength and $L$ is a geometric length scale, and are set up on a time scale $a{u}_c=lambd{a}_{D}L/D$, where $lambd{a}_D$ is the screening length and $D$ is the ionic diffusion constant. We propose and analyze ICEO microfluidic pumps and mixers that operate without moving parts under low applied potentials. Similar flows around metallic colloids with fixed total charge have been described in the Russian literature (largely unnoticed in the West). ICEO flows around conductors with fixed potential, on the other hand, have no colloidal analog and offer further possibilities for microfluidic applications.

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Cited in

(65)

• Net flow of charge-asymmetric electrolytes through uncharged channels and over uncharged spheres due to direct-current electroosmosis
• Dipolophoresis in concentrated suspensions of ideally polarizable spheres
• Flagellar dynamics of chains of active Janus particles fueled by an AC electric field
• Breaking electrolyte symmetry in induced-charge electro-osmosis
• Patterned surface charges coupled with thermal gradients may create giant augmentations of solute dispersion in electro-osmosis of viscoelastic fluids
• Transient electrophoresis of a conducting cylindrical colloidal particle suspended in a Brinkman medium
• Electrohydrodynamic flow about a colloidal particle suspended in a non-polar fluid
• Dynamics and stability of an annular electrolyte film
• Double layer overlap in ac electroosmosis
• Ion steric effects on electrophoresis of a colloidal particle
• Induced-charge electroosmosis, polarization, electrorotation, and traveling-wave electrophoresis of Horn toroidal particles
• ELECTRO-OSMOTIC SLIP OF THE SECOND KIND AND INSTABILITY IN CONCENTRATION POLARIZATION AT ELECTRODIALYSIS MEMBRANES
• Two-dimensional dipolophoretic motion of a pair of ideally polarizable particles under a uniform electric field
• Electrophoretic motion of a non-uniformly charged particle in a viscoelastic medium in thin electrical double layer limit
• Diffusiophoresis in narrow channel flows
• Dipolophoresis of nanoparticles
• Induced-charge electrokinetic flows about polarizable nano-particles: the thick-Debye-layer limit
• Light-induced thermoosmosis about conducting ellipsoidal nanoparticles
• Induced-charge electrophoresis of nonspherical particles
• Tandem droplet locomotion in a uniform electric field
• Dipolophoresis in large-scale suspensions of ideally polarizable spheres
• A unified theory of dipolophoresis for nanoparticles
• Nonlinear interactions in electrophoresis of ideally polarizable particles
• Nonlinear alternating electric field dipolophoresis of spherical nanoparticles
• Macro-scale description of transient electro-kinetic phenomena over polarizable dielectric solids
• Exact solutions for hydrodynamic interactions of two squirming spheres
• Multi-functional Lagrangian flow structures in three-dimensional ac electro-osmotic micro-flows
• A depth-averaged electrokinetic flow model for shallow microchannels
• Surprising consequences of ion conservation in electro-osmosis over a surface charge discontinuity
• A dual-porosity model for ionic solute transport in expansive clays
• Flow and streaming potential of an electrolyte in a channel with an axial temperature gradient
• On electro-osmotic flows through microchannel junctions
• Migration of ion-exchange particles driven by a uniform electric field
• Dielectric-solid polarization at strong fields: Breakdown of Smoluchowski's electrophoresis formula
• A direct matrix method for computing analytical jacobians of discretized nonlinear integro-differential equations
• Boundary-induced electrophoresis of uncharged conducting particles: remote wall approximations
• Electro-hydrodynamic particle levitation on electrodes
• Applications of electrohydrodynamics and Joule heating effects in microfluidic chips: a review
• Convective diffusion from convex microprobes into colloidal suspensions: the edge effects
• Symmetry breaking in induced-charge electro-osmosis over polarizable spheroids
• Stabilization of a suspension of sedimenting rods by induced-charge electrophoresis
• A model for the electric field-driven flow and deformation of a drop or vesicle in strong electrolyte solutions
• Oscillatory electro-osmotic flow through a slit channel with slipping stripes on walls
• The effect of Brownian motion on the stability of sedimenting suspensions of polarizable rods in an electric field
• Osmotic and electroosmotic fluid transport across the retinal pigment epithelium: a mathematical model
• From electrodiffusion theory to the electrohydrodynamics of leaky dielectrics through the weak electrolyte limit
• Fundamental aspects of concentration polarization arising from nonuniform electrokinetic transport
• Electro-convection about conducting particles
• Electroosmosis over non-uniformly charged surfaces: modified Smoluchowski slip velocity for second-order fluids
• Slender-body approximations for electro-phoresis and electro-rotation of polarizable particles
• Stationary electro-osmotic flow driven by AC fields around charged dielectric spheres
• Electrokinetics at liquid/liquid interfaces
• Solvo-osmotic flow in electrolytic mixtures
• A conservative discretization of the Poisson-Nernst-Planck equations on adaptive Cartesian grids
• Electrokinetic locomotion due to reaction-induced charge auto-electrophoresis
• Breaking symmetries in induced-charge electro-osmosis and electrophoresis
• Induced-charge electro-osmosis in dielectric annuli
• Electro-osmotic flows over highly polarizable dielectric surfaces
• Direct simulation on nonlinear thermokinetic phenomena due to induced-charge electroosmosis
• Existence of \(C^{1,\alpha}\) singular solutions to Euler-Nernst-Planck-Poisson system on \(\mathbb{R}^3\) with free-moving charges
• Effect of induced-charge double layer on dielectrophoretic motion of particles
• Lubrication theory for electro-osmotic flow in a non-uniform electrolyte
• Uniqueness of weak solutions to an electrohydrodynamics model
• Electro-osmosis of superimposed fluids in the presence of modulated charged surfaces in narrow confinements
• Fast solvers for models of ICEO microfluidic flows

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