Solvo-osmotic flow in electrolytic mixtures

DOI10.1017/JFM.2017.184zbMATH Open1383.76551arXiv1703.06643OpenAlexW3103778007WikidataQ58221678 ScholiaQ58221678MaRDI QIDQ5364720FDOQ5364720

Authors: Sela Samin, René H. van Roij 

Publication date: 28 September 2017

Published in: Journal of Fluid Mechanics (Search for Journal in Brave)

Abstract: We show that an electric field parallel to an electrically neutral surface can generate flow of electrolytic mixtures in small channels. We term this solvo-osmotic flow, since the flow is induced by the asymmetric preferential solvation of ions at the liquid-solid interface. The generated flow is comparable in magnitude to the ubiquitous electro-osmotic flow at charged surfaces, but for a fixed surface charge density, it differs qualitatively in its dependence on ionic strength. Solvo-osmotic flow can also be sensitively controlled with temperature. We derive a modified Helmholtz-Smoluchowski equation that accounts for these effects.

Full work available at URL: https://arxiv.org/abs/1703.06643

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zbMATH Keywords

micro-/nano-fluid dynamics

Mathematics Subject Classification ID

Magnetohydrodynamics and electrohydrodynamics (76W05)

Cites Work

• Engineering Flows in Small Devices: Microfluidics Toward a Lab-on-a-Chip
• Electro-osmotic flow in two-dimensional charged micro- and nanochannels
• Lubrication theory for electro-osmotic flow in a slit microchannel with the Phan-Thien and Tanner model

Cited In (10)

• Mobility of nanometer-size solutes in water driven by electric field
• Diffusiophoresis in narrow channel flows
• Title not available (Why is that?)
• Uncoupling electrokinetic flow solutions
• Flow and streaming potential of an electrolyte in a channel with an axial temperature gradient
• Net flow of charge-asymmetric electrolytes through uncharged channels and over uncharged spheres due to direct-current electroosmosis
• Electroosmotic flow in sludge flocs
• Exact solution of an electro-osmotic flow problem in a cylindrical channel of polymer electrolyte membranes
• Effects of electric charge on osmotic flow across periodically arranged circular cylinders
• Electrolubrication in liquid mixtures between two parallel plates

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