The nascent coffee ring: how solute diffusion counters advection
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Publication:4957096
Abstract: We study the initial evolution of the coffee ring that is formed by the evaporation of a thin, axisymmetric, surface tension-dominated droplet containing a dilute solute. When the solutal P'{e}clet number is large, we show that diffusion close to the droplet contact line controls the coffee-ring structure in the initial stages of evaporation. We perform a systematic matched asymptotic analysis for two evaporation models -- a simple, non-equilibrium, one-sided model (in which the evaporative flux is taken to be constant across the droplet surface) and a vapour-diffusion limited model (in which the evaporative flux is singular at the contact line) -- valid during the early stages in which the solute remains dilute. We call this the `nascent coffee ring' and describe the evolution of its features, including the size and location of the peak concentration and a measure of the width of the ring. Moreover, we use the asymptotic results to investigate when the assumption of a dilute solute breaks down and the effects of finite particle size and jamming are expected to become important. In particular, we illustrate the limited validity of this model in the diffusive evaporative flux regime.
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Cited in
(21)- Asymptotic analysis of the dominant mechanisms in the coffee extraction process
- The nascent coffee ring with arbitrary droplet contact set: an asymptotic analysis
- Physicochemical hydrodynamics of the phase segregation in an evaporating binary microdroplet
- Patterning of colloidal droplet deposits on soft materials
- Formation of ring structures in a drying under the mask film of colloidal solution
- Coffee stain effect on a fibre from axisymmetric droplets
- Evaporation of non-circular droplets
- Comparison of one-sided and diffusion-limited evaporation models for thin liquid droplets
- Accumulation of Particles Towards the Envelope of a Fluid-Infused Patch Under Evaporation
- Gravitational effects on coffee-ring formation during the evaporation of sessile droplets
- The effect of the spatial variation of the evaporative flux on the deposition from a thin sessile droplet
- Mathematical modelling of impurity deposition during evaporation of dirty liquid in a porous material
- Lattice Boltzmann modelling of diverse particle deposition patterns by droplet evaporation
- Making a deposit: the role of substrate adsorption in coffee-ring formation in sessile evaporating droplets
- Evaporation of sessile droplets
- Evaporation dynamics of wavy sessile droplets
- The effect of particle-substrate adsorption on the deposition of particles from a thin evaporating sessile droplet
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- Non-uniformities in miscible surfactant-laden two-layer thin liquid films
- The effect of contact-line motion on the deposition of particles from an evaporating sessile droplet
- Asymptotic analysis of a kinematic model for coffee-ring deposition
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