EDP-convergence for nonlinear fast–slow reaction systems with detailed balance*

DOI10.1088/1361-6544/AC0A8AzbMATH Open1475.35183arXiv2010.08458OpenAlexW3092980098MaRDI QIDQ5000671FDOQ5000671

Alexander Mielke, Mark A. Peletier, Artur Stephan

Publication date: 15 July 2021

Published in: Nonlinearity (Search for Journal in Brave)

Abstract: We consider nonlinear reaction systems satisfying mass-action kinetics with slow and fast reactions. It is known that the fast-reaction-rate limit can be described by an ODE with Lagrange multipliers and a set of nonlinear constraints that ask the fast reactions to be in equilibrium. Our aim is to study the limiting gradient structure which is available if the reaction system satisfies the detailed-balance condition. The gradient structure on the set of concentration vectors is given in terms of the relative Boltzmann entropy and a cosh-type dissipation potential. We show that a limiting or effective gradient structure can be rigorously derived via EDP convergence, i.e. convergence in the sense of the Energy-Dissipation Principle for gradient flows. In general, the effective entropy will no longer be of Boltzmann type and the reactions will no longer satisfy mass-action kinetics.

Full work available at URL: https://arxiv.org/abs/2010.08458

zbMATH Keywords

gradient structuremass-action kineticsevolutionary gamma convergencedetailed-balance condition

Mathematics Subject Classification ID

Singular perturbations in context of PDEs (35B25) Reaction-diffusion equations (35K57) Variational methods involving nonlinear operators (47J30) Multiple scale methods for ordinary differential equations (34E13) Classical flows, reactions, etc. in chemistry (92E20)

Cites Work

• An introduction to \(\Gamma\)-convergence
• Title not available (Why is that?)
• Title not available (Why is that?)
• Title not available (Why is that?)
• Title not available (Why is that?)
• A gradient structure for reaction–diffusion systems and for energy-drift-diffusion systems
• Local minimization, variational evolution and \(\Gamma\)-convergence
• On the relation between gradient flows and the large-deviation principle, with applications to Markov chains and diffusion
• Separation of time-scales and model reduction for stochastic reaction networks
• On uniform decay of the entropy for reaction-diffusion systems
• An interesting class of partial differential equations
• Non-equilibrium Thermodynamical Principles for Chemical Reactions with Mass-Action Kinetics
• Instantaneous limits of reversible chemical reactions in presence of macroscopic convection.
• On microscopic origins of generalized gradient structures
• A gradient system with a wiggly energy and relaxed EDP-convergence
• Evolutionary Γ-convergence of gradient systems modeling slow and fast chemical reactions
• Coarse-graining via EDP-convergence for linear fast-slow reaction systems
• Exploring families of energy-dissipation landscapes via tilting: three types of EDP convergence
• Modeling of chemical reaction systems with detailed balance using gradient structures

Cited In (9)

• Non-equilibrium steady states as saddle points and EDP-convergence for slow-fast gradient systems
• EDP-convergence for a linear reaction-diffusion system with fast reversible reaction
• A porous-media model for reactive fluid–rock interaction in a dehydrating rock
• On a reversible Gray-Scott type system from energetic variational approach and its irreversible limit
• Existence of similarity profiles for diffusion equations and systems
• Coarse-graining via EDP-convergence for linear fast-slow reaction systems
• Cosh gradient systems and tilting
• Fast reaction limits via \(\Gamma\)-convergence of the flux rate functional
• On self-similar patterns in coupled parabolic systems as non-equilibrium steady states

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