Coarse-graining via EDP-convergence for linear fast-slow reaction systems

DOI10.1142/S0218202520500360zbMATH Open1454.60113arXiv1911.06234OpenAlexW3039887769MaRDI QIDQ3386876FDOQ3386876

Authors: Alexander Mielke, Artur Stephan 

Publication date: 7 January 2021

Published in: M\(^3\)AS. Mathematical Models \& Methods in Applied Sciences (Search for Journal in Brave)

Abstract: We consider linear reaction systems with slow and fast reactions, which can be interpreted as master equations or Kolmogorov forward equations for Markov processes on a finite state space. We investigate their limit behavior if the fast reaction rates tend to infinity, which leads to a coarse-grained model where the fast reactions create microscopically equilibrated clusters, while the exchange mass between the clusters occurs on the slow time scale. Assuming detailed balance the reaction system can be written as a gradient flow with respect to the relative entropy. Focusing on the physically relevant cosh-type gradient structure we show how an effective limit gradient structure can be rigorously derived and that the coarse-grained equation again has a cosh-type gradient structure. We obtain the strongest version of convergence in the sense of the Energy-Dissipation Principle (EDP), namely EDP-convergence with tilting.

Full work available at URL: https://arxiv.org/abs/1911.06234

Recommendations

• EDP-convergence for a linear reaction-diffusion system with fast reversible reaction
• EDP-convergence for nonlinear fast-slow reaction systems with detailed balance
• Evolutionary \(\Gamma\)-convergence of gradient systems modeling slow and fast chemical reactions
• Hypocoercivity and fast reaction limit for linear reaction networks with kinetic transport
• Modeling of chemical reaction systems with detailed balance using gradient structures

zbMATH Keywords

coarse grainingenergy-dissipation balanceEDP-convergencereconstruction operatorsentropic gradient structureMarkov process with detailed balance

Mathematics Subject Classification ID

Applications of Markov chains and discrete-time Markov processes on general state spaces (social mobility, learning theory, industrial processes, etc.) (60J20) Markov semigroups and applications to diffusion processes (47D07) Variational methods involving nonlinear operators (47J30) Classical flows, reactions, etc. in chemistry (92E20)

Cites Work

• Probability. Theory and examples.
• THE GEOMETRY OF DISSIPATIVE EVOLUTION EQUATIONS: THE POROUS MEDIUM EQUATION
• Modern methods in the calculus of variations. \(L^p\) spaces
• The Variational Formulation of the Fokker--Planck Equation
• Title not available (Why is that?)
• Title not available (Why is that?)
• Geometric singular perturbation theory for ordinary differential equations
• Ricci curvature of finite Markov chains via convexity of the entropy
• Fokker-Planck equations for a free energy functional or Markov process on a graph
• Integrals which are convex functionals
• A gradient structure for reaction–diffusion systems and for energy-drift-diffusion systems
• Geodesic convexity of the relative entropy in reversible Markov chains
• On the relation between gradient flows and the large-deviation principle, with applications to Markov chains and diffusion
• Title not available (Why is that?)
• Gradient flows of the entropy for finite Markov chains
• Separation of time-scales and model reduction for stochastic reaction networks
• An interesting class of partial differential equations
• Title not available (Why is that?)
• On Conjugate Convex Functions
• Large deviations in stochastic heat-conduction processes provide a gradient-flow structure for heat conduction
• Non-equilibrium thermodynamical principles for chemical reactions with mass-action kinetics
• Homogenization of Cahn-Hilliard-type equations via evolutionary \(\Gamma\)-convergence
• Instantaneous limits of reversible chemical reactions in presence of macroscopic convection.
• On microscopic origins of generalized gradient structures
• A gradient system with a wiggly energy and relaxed EDP-convergence
• An existence result and evolutionary \(\varGamma \)-convergence for perturbed gradient systems
• Evolutionary \(\Gamma\)-convergence of gradient systems modeling slow and fast chemical reactions
• EDP-convergence for nonlinear fast-slow reaction systems with detailed balance

Cited In (19)

• \( \Gamma \)-compactness and \(\Gamma \)-stability of maximal monotone flows
• Hypocoercivity and fast reaction limit for linear reaction networks with kinetic transport
• Effective diffusion in thin structures via generalized gradient systems and EDP-convergence
• Non-equilibrium steady states as saddle points and EDP-convergence for slow-fast gradient systems
• EDP-convergence for a linear reaction-diffusion system with fast reversible reaction
• Evolutionary \(\Gamma\)-convergence of entropic gradient flow structures for Fokker-Planck equations in multiple dimensions
• Exploring families of energy-dissipation landscapes via tilting: three types of EDP convergence
• Evolutionary \(\Gamma\)-convergence of gradient systems modeling slow and fast chemical reactions
• Quantitative Coarse-Graining of Markov Chains
• Variational methods for evolution. Abstracts from the workshop held September 6--12, 2020 (hybrid meeting)
• Consistency and convergence for a family of finite volume discretizations of the Fokker-Planck operator
• GENERIC framework for reactive fluid flows
• EDP-convergence for nonlinear fast-slow reaction systems with detailed balance
• Jump processes as generalized gradient flows
• Coarse graining of a Fokker–Planck equation with excluded volume effects preserving the gradient flow structure
• Existence of similarity profiles for diffusion equations and systems
• Cosh gradient systems and tilting
• Fast reaction limits via \(\Gamma\)-convergence of the flux rate functional
• Modeling of chemical reaction systems with detailed balance using gradient structures

This page was built for publication: Coarse-graining via EDP-convergence for linear fast-slow reaction systems

Report a bug (only for logged in users!)Click here to report a bug for this page (MaRDI item Q3386876)