Kramers' formula for chemical reactions in the context of Wasserstein gradient flows

DOI10.4310/CMS.2011.V9.N2.A15zbMATH Open1219.35315arXiv1008.3658MaRDI QIDQ548459FDOQ548459

Barbara Niethammer, Michael Herrmann

Publication date: 28 June 2011

Published in: Communications in Mathematical Sciences (Search for Journal in Brave)

Abstract: We derive Kramers' formula as singular limit of the Fokker-Planck equation with double-well potential. The convergence proof is based on the Rayleigh principle of the underlying Wasserstein gradient structure and complements a recent result by Peletier, Savar'e and Veneroni.

Full work available at URL: https://arxiv.org/abs/1008.3658

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zbMATH Keywords

Fokker-Planck equationWasserstein gradient flowRayleigh principleKramers' formula

Mathematics Subject Classification ID

Fokker-Planck equations (35Q84) Variational principles of physics (49S05) Chemical kinetics in thermodynamics and heat transfer (80A30)

Cited In (10)

• Passing to the limit in a Wasserstein gradient flow: from diffusion to reaction
• Mass transport in Fokker–Planck equations with tilted periodic potential
• Title not available (Why is that?)
• Asymptotics for scaled Kramers-Smoluchowski equations in several dimensions with general potentials
• A Semiclassical Approach to the Kramers--Smoluchowski Equation
• Asymptotics for scaled Kramers-Smoluchowski equations
• Rate-independent dynamics and Kramers-type phase transitions in nonlocal Fokker-Planck equations with dynamical control
• Cosh gradient systems and tilting
• Bistable stochastic biochemical networks: large chemical networks and systems with many molecules
• About small eigenvalues of the Witten Laplacian

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