Micro-canonical statistical mechanics of some non-extensive systems

DOI10.1016/S0960-0779(01)00023-6MaRDI QIDQ5954864zbMATH OpenOpenAlexFDO

Authors D. H. E. Gross

Publication date 5 February 2002

Published in Chaos, Solitons and Fractals (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/cond-mat/0004268

zbMATH Keywords

Boltzmann's mechanical definition of entropyphase transitionsstatistical mechanics

Mathematics Subject Classification ID

Foundations of equilibrium statistical mechanics (82B03)

Abstract: Non-extensive systems do not allow to go to the thermodynamic limit. Therefore we have to reformulate statistical mechanics without invoking the thermodynamical limit. I.e. we have to go back to Pre-Gibbsian times. We show that Boltzmann's mechanical definition of entropy S as function of the conserved ``extensive variables energy E, particle number N etc. allows to describe even the most sophisticated cases of phase transitions unambiguously for ``small systems like nuclei, atomic clusters, and selfgravitating astrophysical systems: The rich topology of the curvature of S(E,N) shows the whole ``Zoo of transitions: transitions of 1.order including the surface tension at phase-separation, continuous transitions, critical and multi-critical points. The transitions are the ``catastrophes of the Laplace transform from the ``extensive to the ``intensive variables. Moreover, this classification of phase transitions is much more natural than the Yang-Lee criterion.

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Cites work

• scientific article; zbMATH DE number 3107064 (Why is no real title available?)
• Nonuniform van der Waals theory.
• Possible generalization of Boltzmann-Gibbs statistics.
• Quelques Propriétés Générales De L'intégrale De Configuration D'un Système De Particules Avec Interaction
• Statistical Theory of Equations of State and Phase Transitions. I. Theory of Condensation
• The physics and mathematics of the second law of thermodynamics
• The rate of entropy increase at the edge of chaos

Cited in

(13)

• Ergodic properties of microcanonical observables
• Nonextensive nuclear liquid-gas phase transition
• A new thermodynamics from nuclei to stars
• A possible scheme for classifying phase transitions in the generalized entropy spectrum of a nonhyperbolic system
• Microcanonical foundation for systems with power-law distributions
• scientific article; zbMATH DE number 5605393 (Why is no real title available?)
• Statistical mechanics of exploding phase spaces: ontic open systems
• scientific article; zbMATH DE number 4115714 (Why is no real title available?)
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• EDUCING THE VOLUME OUT OF THE PHASE-SPACE BOUNDARY
• Thermodynamic geometry of Kaniadakis statistics
• On first-order phase transitions in microcanonical and canonical non-extensive systems
• Nonuniqueness of canonical ensemble theory arising from microcanonical basis

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